Research on surface plasmon resonance coupling of metallic nanostructures is an important area in the field of plasmonics because distinctive collective optical properties can be realized that are different from the individual constituents. Here we report the localized surface plasmon resonance of hybrid metal-organic nanorods. Colloidal-dispersed Au-PPy nanorods were synthesized as a representative material using a modified electrochemical method, and the collective oscillation properties were systematically investigated by comparing these materials with pure Au nanorods. We observed the extended surface plasmon resonance of a hybrid system. The presence of doped-PPy segments on Au segments induced an enhanced coherent electric field due to the partial contribution of π-electrons on the PPy segment, which led to a red-shifted plasmon feature. Additionally, we demonstrated that surface plasmon resonance extension can be tuned by dopant anions, which demonstrates a way of tuning a dopant-induced plasmonic system.
In this study, we demonstrate a hybrid multimodal soft magnetic composite (SMC) comprising gas-atomized spherical amorphous powder (AP) and carbonyl-iron powder (CIP), and present its enhanced electromagnetic properties. CIP is selectively incorporated into voids between AP, and deforms during compression, effectively reducing the pores, resulting in high packing density of the core, where CIP magnetically bridges AP and helps magnetic domain rotation much efficiently. The hybrid SMC with the addition of 20 wt.% CIP showed constant effective permeability of 57 up to 1 MHz, a remarkable 63% increase compared with the AP core, while DC bias superimposing retention level of 61% was secured with the help of high magnetization of CIP. In addition, the effect of SiO2 surface insulation, prepared by the sol-gel process, on the high-frequency magnetic properties of hybrid SMCs, was also evaluated. It is thus revealed that the high-frequency dynamic loss of the hybrid core, originating from intra-particle eddy current loss and anomalous loss component, and inter-particle eddy currents are negligibly small. We believe that our approach using AP/CIP multimodal hybrid SMCs is an effective way of achieving high permeability as well as high DC bias characteristics at high frequencies. This process will be highly beneficial for the miniaturization of power inductors.
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