We demonstrate that the electrical property of a single layer molybdenum disulfide (MoS 2 ) can be significantly tuned from semiconducting to insulating regime via controlled exposure to oxygen plasma. The mobility, on-current and resistance of single layer MoS 2 devices were varied up to four orders of magnitude by controlling the plasma exposure time. Raman spectroscopy, X-ray photoelectron spectroscopy and density functional theory studies suggest that the significant variation of electronic properties is caused by the creation of insulating MoO 3 -rich disordered domains in the MoS 2 sheet upon oxygen plasma exposure, leading to an exponential variation of resistance and mobility as a function of plasma exposure time. The resistance variation calculated using an effective medium model is in excellent agreement with the measurements. The simple approach described here can be used for the fabrication of tunable two dimensional nanodevices on MoS 2 and other transition metal dichalcogenides.
We resolve the problem of the violation of single parameter scaling at the zero energy of the Anderson tight-binding model with diagonal disorder. It follows from the symmetry properties of the tight-binding Hamiltonian that this spectral point is, in fact, a boundary between two adjacent bands. The states in the vicinity of this energy behave similarly to states at other band boundaries, which are known to violate single parameter scaling.
Exciton polaritons in one-dimensional photonic crystals based on multiple quantum well structures are investigated. The effects due to interplay between resonant interaction of light with quantum well excitons, and light scattering from well-barrier interface, are elucidated. Polariton dispersion equations and reflection spectra in structures with two wells in an elementary supercell of the periodic structure are studied. Several examples of different compound elementary supercells are considered. Special attention is paid to structures with the period or the distance between quantum wells satisfying the resonance Bragg condition. Such structures are characterized by a presence of a larger-than-usual polariton stop band. It is shown that in structures with a complex elementary supercell, the width of such a stop band can be significantly enhanced in comparison to that in simple structures.
A detailed first-principle study has been performed to evaluate the electronic and optical properties of single-layer (SL) transition metal dichalcogenides (TMDCs) (MX2; M= transition metal such as Mo, W and X= S, Se, Te), in the presence of vacancy defects (VDs). Defects usually play an important role in tailoring electronic, optical, and magnetic properties of semiconductors. We consider three types of VDs in SL TMDCs i) X-vacancy, X2-vacancy, and iii) M -vacancy. We show that VDs lead to localized defect states (LDS) in the band structure, which in turn give rise to sharp transitions in in-plane and out-of-plane optical susceptibilities, χ and χ ⊥ . The effects of spin orbit coupling (SOC) are also considered. We find that SOC splitting in LDS is directly related to the atomic number of the transition metal atoms. Apart from electronic and optical properties we also find magnetic signatures (local magnetic moment of ∼ µB) in MoSe2 in the presence of Mo vacancy, which breaks the time reversal symmetry and therefore lifts the Kramers degeneracy. We show that a simple qualitative tight binding model (TBM), involving only the hopping between atoms surrounding the vacancy with an on-site SOC term, is sufficient to capture the essential features of LDS. In addition, the existence of the LDS can be understood from the solution of the 2D Dirac Hamiltonian by employing infinite mass boundary conditions. In order to provide a clear description of the optical absorption spectra, we use group theory to derive the optical selection rules between LDS for both χ and χ ⊥ . arXiv:1704.02023v1 [cond-mat.mes-hall]
We describe a novel effect of the generation of direct current which may arise in semiconductors or semiconductor microstructures due to a mixing of coherent electromagnetic radiations of commensurate frequencies. The effect is, in essence, due to a nonparabolicity of the electron energy bands and is stronger in systems where this nonparabolicity is greater. We have made exact calculations in the framework of the Kane model, applicable to narrow gap semiconductors and the tight-binding model which we employ for a description of a semiconductor superlattice. 72.20.Ht,42.65.Hw
We numerically study the distribution function of the conductivity (transmission) in the onedimensional tight-binding Anderson model in the region of fluctuation states. We show that while single parameter scaling in this region is not valid, the distribution can still be described within a scaling approach based upon the ratio of two fundamental quantities, the localization length, l loc , and a new length, ls, related to the integral density of states. In an intermediate interval of the system's length L, l loc ≪ L ≪ ls, the variance of the Lyapunov exponent does not follow the predictions of the central limit theorem, and may even grow with L.
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