Previously it was shown that wood chip compression or enzyme impregnation prior to refining reduces energy consumption and improves pulp quality. This work characterizes the effect of different magnitudes and rates of compression on the extent of enzymatic hydrolysis. A laboratory compressor and a controlled uniaxial load set-up were used to apply different compression ratios and compression times to mixed-softwood wood chips. The chips were subsequently subjected to enzymatic hydrolysis with a high-yield exoglucanase preparation to demonstrate changes in cellulose hydrolysis. Enzymatic hydrolysis yield increased with compression ratio but was unaffected by compression time. Increasing compression ratio increased removal of soluble molecules such as sugars and acid-soluble lignin. Microscopy imaging showed increased cell wall buckling and fracturing with increased compression. The morphological changes led to improved enzyme diffusion and resulted in higher available surface area. The improved cellulose hydrolysis is due to changes in wood morphology as well as the removal of extractives.
An experimental and computational investigation of the internal flow of elastoviscoplastic fluids over nonsmooth topologies is presented in two complimentary studies. In the first study, we visualize the creeping flow of a Carbopol gel over a cavity embedded in a thin slot using Optical Coherence Tomography (OCT) and confocal microscopy. We measure the size and shape of the plug as a function of Bingham and Weissenberg numbers. An asymmetry in the plug shape is observed which is also evident in our second study-numerical simulations using adaptive finite element method based upon an augmented Lagrangian scheme. We quantify the asymmetry and present the results as a function of the product of the Weissenberg and Bingham numbers which collapse onto a single curve for each of these geometries. These findings underscore the theoretical underpinnings of the synergy between elasticity and plasticity of these complex fluids.
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