No abstract

This study presents an extension of the concept of ''quasi-saturation'' to a quasi-saturated layer, defined as the uppermost dynamic portion of the saturated zone subject to water table fluctuations. Entrapped air here may cause substantial reductions in the hydraulic conductivity (K ) and fillable pore water. Air entrapment is caused by a rising water table, usually as a result of groundwater recharge. The most significant effects of entrapped air are recharge overestimation based on methods that use specific yield (S y ), such as the water table fluctuation method (WTF), and reductions in K values. These effects impact estimation of fluid flow velocities and contaminant migration rates in groundwater. In order to quantify actual groundwater recharge rates and the effects of entrapped air, numerical simulations with the FEFLOW (Version 7.0) groundwater flow model were carried out using a quasi-saturated layer for a pilot area in Rio Claro, Brazil. The calculated recharge rate represented 16% of the average precipitation over an 8-year period, approximately half of estimates using the WTF method. Air entrapment amounted to a fillable porosity of 0.07, significant lower that the value of 0.17 obtained experimentally for S y . Numerical results showed that the entrapped air volume in the quasi-saturated layer can be very significant (0.58 of the air fraction) and hence can significantly affect estimates of groundwater recharge and groundwater flow rates near the water table. Article impact statement: Quasi-saturation due to air entrapment near the water table has major effects on estimated recharge rates and modeling groundwater.

Many soil, hydrologic and environmental applications require information about the unsaturated soil hydraulic properties. The evaporation method has long been used for estimating the drying branches of the soil hydraulic functions. An increasingly popular version of the evaporation method is the semi-automated HYPROP © measurement system (HMS) commercialized by Decagon Devices (Pullman, WA) and UMS AG (München, Germany). Several studies were previously carried out to test the HMS methodology by using the Richards equation and the van-Genuchten-Mualem (VG) or Kosugi-Mualem soil hydraulic functions to obtain synthetic data for use in the HMS analysis, and then to compare results against the original hydraulic properties. Using HYDRUS-1D, we carried out independent tests of the HYPROP system as applied to the VG functions for a broad range of soil textures. Our results closely agreed with previous findings. Accurate estimates were especially obtained for the soil water retention curve and its parameters, at least over the range of available retention measurements. We also successfully tested a dual-porosity soil, as well as an extremely coarse medium with a very high van Genuchten n value. The latter case gave excellent results for water retention, but failed for the hydraulic conductivity. In many cases, especially for soils with intermediate and high n values, an independent estimate of the saturated hydraulic conductivity should be obtained. Overall, the HMS methodology performed extremely well and as such constitutes a much-needed addition to current soil hydraulic measurement techniques.

No abstract

Sugarcane vinasse is a residue generated at a rate fifteen times greater than the ethanol production. Because of its high organic and micronutrient content, this residue is used as a fertilizer on sugarcane crops. However, when used in large quantities, vinasse can saturate the soil and contaminate nearby water resources by percolation and leaching. Given the proven toxic potential of in natura vinasse, the present study aimed to evaluate the toxic potential of leached sugarcane vinasse using Nile tilapia (Oreochromis niloticus) as a test organism. A bioassay was performed after vinasse percolation in laboratory soil columns. The bioassay included one control group containing fresh water and two treatment groups, the first exposed to a 2,5% dilution of leached of vinasse and the second to a 2,5% dilution of in natura vinasse. After exposure, histopathological analysis was performed in gills and livers, and the latter were labelled for HSP70 proteins. No significant changes were detected in the gills of the exposed fish. However, in the liver, both in natura and leached vinasse induced statistically significant histopathological changes. These changes include hydropic degeneration, cell boundary losses, pyknotic nuclei and cellular disorganization. HSP70 expression significant increase in liver of both treatment groups were observed, being higher for the in natura vinasse exposed group. Results suggested that both leached vinasse and in natura vinasse were toxic, its still able to provoke histological changes and induce the cytoprotective response in exposed fish liver, evidenced by a immunostaining of cellular stress proteins. Thus, in order to reduce its environmental impact, appropriated effluent disposal is essential.