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Future fuels for compression ignition engines will be required both to reduce the anthropogenic carbon dioxide emissions from fossil sources and to contribute to the reductions in the exhaust levels of pollutants, such as nitrogen oxides and particulate matter. Via various processes of biological, chemical and physical conversion, feedstocks such as lignocellulosic biomass and photosynthetic micro-organisms will yield a wide variety of potential fuel molecules. Furthermore, modification of the production processes may allow the targeted manufacture of fuels of specific molecular structure. This paper therefore presents an overview of the effects of fuel molecular structure on the combustion and emissions characteristics of compression ignition engines, highlighting in particular the submolecular features common to a variety of potential fuels. An increase in the straight-chain length of the alkyl moiety reduces the duration of ignition delay, and the introduction of double bonds or branching to an alkyl moiety both increase ignition delay. The movement of a double bond towards the centre of an alkyl chain, or the addition of oxygen to a molecule, can both increase and decrease the duration of ignition delay dependent on the overall fuel structure. Nitrogen oxide emissions are primarily influenced by the duration of fuel ignition delay, but in the case of hydrogen and methane pilot-ignited premixed combustion arise only at flame temperatures sufficiently high for thermal production. An increase in aromatic ring number and physical properties such as the fuel boiling point increase particulate matter emissions at constant combustion phasing.

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The paper presents an experimental investigation of combusting methane-hydrogen mixtures, pilotignited by diesel fuel, on a naturally aspirated, direct injection compression ignition engine. The tests were performed with two diesel fuel flow rates for pilot-ignition, and the engine was supplied with different quantities of methane-hydrogen mixtures (in various proportions) to vary the engine load between 0 and 7 bar IMEP. In addition, engine in-cylinder gas samples were collected with two geometric sampling arrangements and at various instants during the engine cycle, to measure species concentrations within the engine cylinder. The results showed lower exhaust CO2 and particulate emissions at all engine loads when combusting methane-hydrogen mixtures as compared to diesel fuel only. CO and unburned THC emissions were higher for methane-hydrogen mixtures at all engine loads when compared with diesel fuel only. NOx emissions increased with increasing proportion of hydrogen in the aspirated mixture at all engine loads. In-cylinder NOx levels were observed to be higher in the region between the fuel sprays as compared to within the spray core, attributable to higher temperatures reached in between the sprays post ignition.

Hydrogen is receiving increasing attention as a versatile energy vector to help accelerate the transition to a decarbonised energy future. Gas turbines will continue to play a critical role in providing grid stability and resilience in future low-carbon power systems; however, it is recognised that this role is contingent upon achieving increased thermal efficiencies and the ability to operate on carbon-neutral fuels such as hydrogen. An important consideration in the development of gas turbine combustors capable of operating with pure hydrogen or hydrogen-enriched natural gas are the significant changes in thermoacoustic instability characteristics associated with burning these fuels. This article provides a review of the effects of burning hydrogen on combustion dynamics with focus on swirl-stabilised lean-premixed combustors. Experimental and numerical evidence suggests hydrogen can have either a stabilising or destabilising impact on the dynamic state of a combustor through its influence particularly on flame structure and flame position. Other operational considerations such as the effect of elevated pressure and piloting on combustion dynamics as well as recent developments in micromix burner technology for 100% hydrogen combustion have also been discussed. The insights provided in this review will aid the development of instability mitigation strategies for high hydrogen combustion.

Polycyclic aromatic hydrocarbons (PAHs) are the carcinogenic components of soot. Detailed understanding of PAH formation characteristics is required for development of effective strategies to curtail PAH formation and reduce soot in combustion devices. This study presents an experimental methodology to analyse PAH formation characteristics of a non-premixed methane-air flame with and without hydrogen (H2) addition, using simultaneous planar laser induced fluorescence (PLIF) imaging of PAH and hydroxyl radical (OH). OH PLIF was used to represent peak temperature regions in the flame front. One-dimensional, opposed-jet laminar non-premixed flame simulations were also carried out for the same fuel mixture conditions. This work describes comparison of trends from both sets of studies. PAH fluorescence intensity values were observed to increase with increasing height above burner, however this rate of increase reduced with H2 addition. This observed rate of change in PAH fluorescence (that is, PAH growth characteristics) is indicative of the sooting potential of the fuel mixture. PAH fluorescence from experiments and PAH concentration from simulation show strong reduction with increase in H2 addition. The percentage reduction in PAH fluorescence signal with H2 addition closer to the burner tip was of a similar magnitude to that observed with flame simulations. The reduction in PAH with H2 addition could be attributed to the reduction in acetylene and propargyl concentrations, and reduced H-abstraction rates, which reduced the availability of active sites for PAH growth. The proposed experimental methodology for PAH measurements can be readily applied to any fuel mixtures.

While lean combustion in gas turbines is known to reduce NOx, it makes combustors more prone to thermo-acoustic instabilities, which can lead to deterioration in engine performance. The work presented in this study investigates the effectiveness of secondary injection of hydrogen to imperfectly premixed methane and ethylene flames in reducing heat release oscillations. Both acoustically forced and unforced flames were studied, and simultaneous OH and H atom PLIF (planar laser induced fluorescence) was conducted. The tests were carried out on a laboratory scale bluff-body combustor with a central V-shaped bluff body. Two-microphone method was used to estimate velocity perturbations from pressure measurements, flame boundary images were captured using high speed Mie scattering, while global heat release fluctuations were determined from OH* chemiluminescence. The results showed that hydrogen addition considerably reduced heat release oscillations for both methane and ethylene flames at all the forcing frequencies tested, with the exception of methane flames forced at 315 Hz, where oscillations increased with hydrogen addition. The addition of hydrogen reduced the extent of flame roll-up for both methane and ethylene flames, however, this reduction was larger for methane flames. NOx exhaust emissions were observed to increase with hydrogen addition for both methane and ethylene flames, with absolute NOx concentrations higher for ethylene flames, due to higher flame temperatures.

This paper reports an experimental investigation into the effects of fuel composition on the exhaust emission of toxic polycyclic aromatic hydrocarbons (PAHs) from a diesel engine, operated at both constant fuel injection and constant fuel ignition modes. The paper quantifies the US EPA (United State Environmental Protection Agency) 16 priority PAHs produced from combustion of fossil diesel fuel and several model fuel blends of n-heptane, toluene and methyl decanoate in a single-cylinder diesel research engine based on a commercial light duty automotive engine. It was found that the level of total PAHs emitted by the various fuel blends decreased with increasing fuel ignition delay and premixed burn fraction, however, where the ignition delay of a fuel blend was decreased with use of an ignition improving additive the level of particulate phase PAH also decreased. Increasing the level of toluene present in the fuel blends decreased levels of low toxicity of two to four ring PAH, while displacing n-heptane with methyl decanoate increased particulate phase adsorbed PAH. Overall, the composition of the fuels investigated was found to have more influence on the concentration of exhaust PAHs formed than that of combustion characteristics, including ignition delay, peak heat release rate and the extent of the premixed burn fractions.