The FTIR and MAX-DOAS daily mean total columns agree very well: no significant bias is observed and the standard deviation of the comparisons is only 8%. Both FTIR and MAX-DOAS HCHO total columns are in good agreement with SCIAMACHY values in the 2004-2005 period, with standard deviations of 21% and 31%, respectively. The same seasonal cycle is observed by the different instruments, with a minimum in austral winter and a maximum in FebruaryMarch.The FTIR and MAX-DOAS data are confronted with HCHO columns calculated by a global CTM, the IMAGES model. The model underestimates the HCHO columns by 23-29% in comparison with FTIR, and by 15% in comparison with DOAS. This bias might have multiple causes, including an underestimation of OH concentrations in the model (as indicated by a sensitivity study using prescribedCorrespondence to: C. Vigouroux (corinne.vigouroux@aeronomie.be) OH fields) and/or an underestimated contribution of largescale transport of HCHO precursors from Madagascar. The latter hypothesis is comforted by the large observed day-today variability of HCHO columns, and by the observation that the peak values of FTIR columns can often be associated with free tropospheric transport patterns from source regions over Madagascar to Réunion Island, according to simulations performed with the Lagrangian particle dispersion model FLEXPART.
Absorption cross sections of SO2 have been recorded at 295 K at the resolutions of 2 and 16 cm−1. The 27000‐ to 40000‐cm−1 spectral region has been investigated. The comparison with data available from the literature shows a good agreement between the different data sets (less than 5%). However, local discrepancies, for example at the peaks of absorption, can reach 20%.
New high-resolution water vapor absorption spectra were obtained at room temperature in the 4200-6600 cm À1 spectral region by combining Fourier transform spectrometers (FTS) with single and multiple reflection cells. With absorption paths from 0.3 to 1800 m in pure and air diluted water vapor, accurate measurements of about 10400 lines in an intensity range from 10 À29 to 10 À19 cm/molecule have been performed. Positions, intensities, self-and air-broadening coefficients and air-induced shifts were determined for the H 2 16 O, H 2 17 O, H 2 18 O and HDO isotopologues. The rovibrational assignment of the observed lines was performed with the use of global variational predictions and allowed the identification of several new energy levels. One major contribution of this work consists of the identification of 3280 new weak lines. A very close agreement between the new measured parameters and those listed in the database is reported as well as between the observations and the most recent variational calculations for the positions and the intensities. The present parameters provide an extended and homogeneous data set for water vapor, which is shown to significantly improve the databases for atmospheric applications, especially in the transmission windows on both sides of the band centered at 5400 cm À1 .
New long path length, high resolution, Fourier transform spectrometer measurements for water are presented. These spectra cover the near infrared, visible, and near ultraviolet regions and contain water transitions belonging to all polyads from 3 to 8. Transitions in the range 13 100-21 400 cm Ϫ1 are analyzed using line lists computed using variational first-principles calculations. 2286 new transitions are assigned to H 2 16 O. These result in the observation of transitions in 15 new overtone and combination bands of water. Energy levels for these and other newly observed levels are presented. It is suggested that local mode rather than normal mode vibrational assignments are more appropriate for the vibrational states of water in polyads 4 and above.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.