The aspect of safety in electronic devices has turned out to be a huge challenge for the world of science. Thus far, satisfactory power and energy densities, efficiency, and cell capacities have been achieved. Unfortunately, the explosiveness and thermal runaway of the cells prevents them from being used in demanding applications such as electric cars at higher temperatures. The main aim of this review is to highlight different electrolytes used in lithium-ion cells as well as the flammability aspect. In the paper, the authors present liquid inorganic electrolytes, composite polymer–ceramic electrolytes, ionic liquids (IL), polymeric ionic liquids, polymer electrolytes (solvent-free polymer electrolytes (SPEs), gel polymer electrolytes (GPEs), and composite polymer electrolytes (CPEs)), and different flame retardants used to prevent the thermal runaway and combustion of lithium-ion batteries (LIBs). Additionally, various flame tests used for electrolytes in LIBs have been adopted. Aside from a detailed description of the electrolytes consumed in LIBs. Last section in this work discusses hydrogen as a source of fuel cell operation and its practical application as a global trend that supports green chemistry.
The article discusses the results of tests carried out under real operating conditions, based on which a custom test for road-rail vehicles was developed. The proposed test reflects the working conditions in which road-rail vehicles are used. The measurements were performed for a vehicle equipped with an internal combustion engine during five stages of operation. Measuring cycles included driving on a paved road, rolling on tracks and running on a track without load, with a load of 90 tons and with a load of 140 tons. The article compares the legislative guidelines with actual operation, thanks to which guidelines for the road-rail test for assessing the exhaust emission of harmful gases were developed. Based on the recorded data, a test proposal was described, taking into account the operating time share during the test, the average speed of travel and the duration of the test cycle. In addition, guidelines on the test procedure in the proposed test are discussed.
Road transport holds for the largest share in the freight transport sector in Europe. This work is carried out by heavy vehicles of various types. It is assumed that, in principle, transport should take place on the main road connections, such as motorways or national roads. Their share in the polish road infrastructure is not dominant. Rural and communal roads roads are the most prevalent. This fact formed the basis of the exhaust emissions and fuel consumption tests of heavy vehicles in real operating conditions. A set of vehicles (truck tractor with a semi-trailer) meeting the Euro V emission norm, transporting a load of 24,800 kg, was selected for the tests. The research was carried out on an non-urban route, the test route length was 22 km. A mobile Semtech DS instrument was used, which was used to measure the exhaust emissions. Based on the obtained results, the emission characteristics were determined in relation to the operating parameters of the vehicles drive system. Road emission, specific emission and fuel consumption values were also calculated.
The article presents issues related to the assessment of concentrations of harmful substances in the exhaust gas cloud behind the vehicle. In the theoretical part, considerations about the harmfulness of exhaust gases and methods of detection of chemical compounds were made, and the issues of von Karman vortices and the Lambert-Beer law were referred to. The test object was a vehicle equipped with an SI engine meeting the Euro 3 standard. The drive unit had a capacity of 2.8 dm3, a rated power reaching 142 kW at 5500 rpm and a maximum torque of 280 Nm at 3500 rpm. The measurements of the dilution of the exhaust gas cloud behind the vehicle were made in stationary conditions (laboratory) and during actual operation in the Poznań agglomeration. In the research, technically advanced equipment from the PEMS group was used. In the analysis of the obtained results, detailed considerations were made regarding the influence of the location of the measuring probe in relation to the exhaust system. As can be seen from the obtained dependencies, the vehicle motion is favorable for the assessment of concentrations behind a moving object, because the ecological indicators at successive distances behind the exhaust system achieve better parameters in most points than in a stationary test.
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