The “naked” fluoride [NMe4]F in CH2Cl2 converts the salt‐like compound [C6F5Xe][AsF6] into the asymmetric, hypervalent molecule 1 in 70 % yield. As a result of its high fluoride‐donating ability and its permanent dipole moment, 1 reacts in good yields with Cd(C6F5)2 to form Xe(C6F5)2 (2) and with Me3SiCN to form C6F5XeCN (3).
„Nacktes Fluorid“ [NMe4]F setzt sich in CH2Cl2 mit der salzartigen Verbindung [C6F5Xe][AsF6] in 70 % Ausbeute zum asymmetrisch hypervalenten Molekül 1 um. Dank seiner hohen Fluoriddonorfähigkeit und seines permanenten Dipolmoments reagiert 1 in guten Ausbeuten mit Cd(C6F5)2 zu 2 und mit Me3SiCN zu 3.
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