Exoplanetary transmission spectroscopy in the near-infrared using Hubble/NICMOS is currently ambiguous because different observational groups claim different results from the same data, depending on their analysis methodologies. Spatial scanning with Hubble/WFC3 provides an opportunity to resolve this ambiguity. We here report WFC3 spectroscopy of the giant planets HD 209458b and XO-1b in transit, using spatial scanning mode for maximum photon-collecting efficiency. We introduce an analysis technique that derives the exoplanetary transmission spectrum without the necessity of explicitly decorrelating instrumental effects, and achieves nearly photon-limited precision even at the high flux levels collected in spatial scan mode. Our errors are within 6% (XO-1) and 26% (HD 209458b) of the photon-limit at a resolving power of λ/δλ ∼ 70, and are better than 0.01% per spectral channel. Both planets exhibit water absorption of approximately 200 ppm at the water peak near 1.38 µm. Our result for XO-1b contradicts the much larger absorption derived from NICMOS spectroscopy. The weak water absorption we measure for HD 209458b is reminiscent of the weakness of sodium absorption in the first transmission spectroscopy of an exoplanet atmosphere by Charbonneau et al. (2002). Model atmospheres having uniformly-distributed extra opacity of 0.012 cm 2 g −1 account approximately for both our water measurement and the sodium absorption. Our results for HD 209458b support the picture advocated by Pont et al. (2013) in which weak molecular absorptions are superposed on a transmission spectrum that is dominated by continuous opacity due to haze and/or dust. However, the extra opacity needed for HD 209458b is grayer than for HD 189733b, with a weaker Rayleigh component.

Neptune-sized extrasolar planets that orbit relatively close to their host stars-often called "hot Neptunes"-are common within the known population of exoplanets and planetary candidates. Similar to our own Uranus and Neptune, inefficient accretion of nebular gas is expected produce hot Neptunes whose masses are dominated by elements heavier than hydrogen and helium. At high atmospheric metallicities of 10-10,000 times solar, hot Neptunes will exhibit an interesting continuum of atmospheric compositions, ranging from more Neptune-like, H 2 -dominated atmospheres to more Venus-like, CO 2 -dominated atmospheres. We explore the predicted equilibrium and disequilibrium chemistry of generic hot Neptunes and find that the atmospheric composition varies strongly as a function of temperature and bulk atmospheric properties such as metallicity and the C/O ratio. Relatively exotic H 2 O, CO, CO 2 , and even O 2 -dominated atmospheres are possible for hot Neptunes. We apply our models to the case of GJ 436b, where we find that a CO-rich, CH 4 -poor atmosphere can be a natural consequence of a very high atmospheric metallicity. From comparisons of our results with Spitzer eclipse data for GJ 436b, we conclude that although the spectral fit from the high-metallicity forward models is not quite as good as the best fit obtained from pure retrieval methods, the atmospheric composition predicted by these forward models is more physically and chemically plausible in terms of the relative abundance of major constituents. High-metallicity atmospheres (orders of magnitude in excess of solar) should therefore be considered as a possibility for GJ 436b and other hot Neptunes.

High-resolution spectroscopy (R ≥ 25, 000) has recently emerged as one of the leading methods for detecting atomic and molecular species in the atmospheres of exoplanets. However, it has so far been lacking a robust method to extract quantitative constraints on the temperature structure and molecular/atomic abundances. In this work, we present a novel Bayesian atmospheric retrieval framework applicable to high-resolution cross-correlation spectroscopy (HRCCS) that relies on the cross-correlation between data and models for extracting the planetary spectral signal. We successfully test the framework on simulated data and show that it can correctly determine Bayesian credibility intervals on atmospheric temperatures and abundances, allowing for a quantitative exploration of the inherent degeneracies. Furthermore, our new framework permits us to trivially combine and explore the synergies between HRCCS and low-resolution spectroscopy (LRS) to maximally leverage the information contained within each. This framework also allows us to quantitatively assess the impact of molecular line opacities at high resolution. We apply the framework to VLT CRIRES K-band spectra of HD 209458 b and HD 189733 b and retrieve abundant carbon monoxide but subsolar abundances for water, which are largely invariant under different model assumptions. This confirms previous analysis of these datasets, but is possibly at odds with detections of H 2 O at different wavelengths and spectral resolutions. The framework presented here is the first step toward a true synergy between space observatories and ground-based high-resolution observations.

We introduce a thermochemical kinetics and photochemical model. We use high-temperature bidirectional reaction rates for important H, C, O, and N reactions (most importantly for CH 4 to CO interconversion), allowing us to attain thermochemical equilibrium, deep in an atmosphere, purely kinetically. This allows the chemical modeling of an entire atmosphere, from deep-atmosphere thermochemical equilibrium to the photochemically dominated regime. We use our model to explore the atmospheric chemistry of cooler (T eff < 10 3 K) extrasolar giant planets. In particular, we choose to model the nearby hot-Neptune GJ436b, the only planet in this temperature regime for which spectroscopic measurements and estimates of chemical abundances now exist. Recent Spitzer measurements with retrieval have shown that methane is driven strongly out of equilibrium and is deeply depleted on the day side of GJ436b, whereas quenched carbon monoxide is abundant. This is surprising because GJ436b is cooler than many of the heavily irradiated hot Jovians and thermally favorable for CH 4 , and thus requires an efficient mechanism for destroying it. We include realistic estimates of ultraviolet flux from the parent dM star GJ436, to bound the direct photolysis and photosensitized depletion of CH 4 . While our models indicate fairly rich disequilibrium conditions are likely in cooler exoplanets over a range of planetary metallicities, we are unable to generate the conditions for substantial CH 4 destruction. One possibility is an anomalous source of abundant H atoms between 0.01 and 1 bars (which attack CH 4 ), but we cannot as yet identify an efficient means to produce these hot atoms.

We present thermal phase curve measurements for the hot Jupiter WASP-103b observed with Hubble/WFC3 and Spitzer /IRAC. The phase curves have large amplitudes and negligible hotspot offsets, indicative of poor heat redistribution to the nightside. We fit the phase variation with a range of climate maps and find that a spherical harmonics model generally provides the best fit. The phase-resolved spectra are consistent with blackbodies in the WFC3 bandpass, with brightness temperatures ranging from 1880 ± 40 K on the nightside to 2930 ± 40 K on the dayside. The dayside spectrum has a significantly higher brightness temperature in the Spitzer bands, likely due to CO emission and a thermal inversion. The inversion is not present on the nightside. We retrieved the atmospheric composition and found the composition is moderately metal-enriched ([M/H] = 23 +29 −13 × solar) and the carbon-to-oxygen ratio is below 0.9 at 3 σ confidence. In contrast to cooler hot Jupiters, we do not detect spectral features from water, which we attribute to partial H 2 O dissociation. We compare the phase curves to 3D general circulation models and find magnetic drag effects are needed to match the data. We also compare the WASP-103b spectra to brown dwarfs and young directly imaged companions and find these objects have significantly larger water features, indicating that surface gravity and irradiation environment play an important role in shaping the spectra of hot Jupiters. These results highlight the 3D structure of exoplanet atmospheres and illustrate the importance of phase curve observations for understanding their complex chemistry and physics.