We have derived new very accurate abundances of the Fe-group elements Sc through Zn (Z = 21−30) in the bright main-sequence turnoff star HD 84937, based on high-resolution spectra covering the visible and ultraviolet spectral regions. New or recent laboratory transition data for 14 species of seven elements have been used. Abundances from more than 600 lines of non-Fe species have been combined with about 550 Fe lines in HD 84937 to yield abundance ratios of high precision. The abundances have been determined from both neutral and ionized transitions, which generally are in agreement with each other. We find no substantial departures from standard LTE Saha ionization balance in this [Fe/H] = −2.32 star. Noteworthy among the abundances are: [Co/Fe] = +0.14 and [Cu/Fe] = −0.83, in agreement with past studies abundance trends in this and other low metallicity stars; and [Sc,Ti,V/Fe] = +0.31, which has not been noted previously. A detailed examination of scandium, titanium, and vanadium abundances in large-sample spectroscopic surveys reveals that they are positively correlated in stars with [Fe/H] < −2; HD 84937 lies at the high end of this correlation. These trends constrain the synthesis mechanisms of Fe-group elements. We also examine the GCE abundance trends of the Fe-group elements, including a new nucleosynthesis model with jet-like explosion effects.

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Atomic transition probability measurements for 364 lines of Ti II in the UV through near IR are reported. Branching fractions from data recorded using a Fourier transform spectrometer and a new echelle spectrometer are combined with published radiative lifetimes to determine these transition probabilities. The new results are in generally good agreement with previously reported FTS measurements. Use of the new echelle spectrometer, independent radiometric calibration methods, and independent data analysis routines enables a reduction of systematic errors and overall improvement in transition probability accuracy over previous measurements.The new Ti II data are applied to high resolution visible and UV spectra of the Sun and metalpoor star HD 84937 to derive new, more accurate Ti abundances. Lines covering a range of wavelength and excitation potential are used to search for non-LTE effects. The Ti abundances derived using Ti II for these two stars match those derived using Ti I and support the relative Ti/Fe abundance ratio versus metallicity seen in previous studies.

Atomic transition probability measurements for 371 Ni I lines in the UV through near IR are reported. Branching fractions from data recorded using a Fourier transform spectrometer and a new echelle spectrograph are combined with published radiative lifetimes to determine these transition probabilities. Generally good agreement is found in comparisons to previously reported Ni I transition probability measurements. Use of the new echelle spectrograph, independent radiometric calibration methods, and independent data analysis routines enable a reduction of systematic errors and overall improvement in transition probability uncertainty over previous measurements. The new Ni I data are applied to high resolution visible and UV spectra of the Sun and metal-poor star HD 84937 to derive new, more accurate Ni abundances. Lines covering a wide range of wavelength and excitation potential are used to search for non-LTE effects.log 10 (N X /N Y ) star -log 10 (N X /N Y )⊙. For element X, the "absolute" abundance is written log ε(X) = log 10 (N X /N H ) + 12. Metallicity we be considered equivalent to the [Fe/H] value.

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