Cell voltage is a fundamental quantity used to monitor and control Li-ion batteries. The open circuit voltage (OCV) is of particular interest as it is believed to be a thermodynamic...
Understanding the role of the phase transitions during lithiation and delithiation of graphite remains a problem of fundamental importance, but also practical relevance owing to its widespread use as the anode material in most commercial lithium-ion cells. Previously performed density functional theory (DFT) calculations show a rapid change in the lithium-carbon interaction at low occupation, due to partial charge transfer from Li to C. We integrate this effect in our previously developed two level mean field model, which describes the Stage I-Stage II transition in graphite. The modified model additionally describes the most predominant transition that occurs at low Li content in graphite, which results in a previously unexplained feature in voltage and dQ/dV profiles, and thermodynamic measurements of partial molar enthalpy. In contrast with the Stage I-Stage II transition, this extra feature is not associated with observable features in the partial molar entropy and our model demonstrates why. There is a sharp change in the open circuit voltage at very low Li occupation, followed by a transition to a voltage plateau (peak in dQ/dV). The behaviour arises due to the contrasting effects of the partial molar entropy and enthalpy terms on the partial molar Gibbs energy and hence cell voltage. Hence the voltage profile and phase transitions can be approximated for all lithium occupations, potentially allowing a predictive capability in cell level models.
Measurements of the open circuit voltage of Li-ion cells have been extensively used as a non-destructive characterisation tool. Another technique based on entropy change measurements has also been applied for this purpose. More recently, both techniques have been used to make qualitative statements about aging in Li-ion cells. One proposed cause of cell failure is point defect formation in the electrode materials. The steps in voltage profiles, and the peaks in entropy profiles are sensitive to order/disorder transitions arising from Li/vacancy configurations, which are affected by the host lattice structures. We compare the entropy change results, voltage profiles and incremental capacity (dQ/dV) obtained from coin cells with spinel lithium manganese oxide (LMO) cathodes, Li1+yMn2-yO4, where excess Li y was added in the range 0 ≤ y ≤ 0.2. A clear trend of entropy and dQ/dV peak amplitude decrease with excess Li amount was determined. The effect arises, in part, from the presence of pinned Li sites, which disturb the formation of the ordered phase. We modelled the voltage, dQ/dV and entropy results as a function of the interaction parameters and the excess Li amount, using a mean field approach. For a given pinning population, we demonstrated that the asymmetries observed in the dQ/dV peaks can be modelled by a single linear correction term. To replicate the observed peak separations, widths and magnitudes, we had to account for variation in the energy interaction parameters as a function of the excess Li amount, y. All Li-Li repulsion parameters in the model increased in value as the defect fraction, y, increased. Our paper shows how far a computational mean field approximation can replicate experimentally observed voltage, incremental capacity and entropy profiles in the presence of phase transitions.
In-situ diagnostic tools have become established to as a means to understanding the aging processes that occur during charge/discharge cycles in Li-ion batteries (LIBs). One electrochemical thermodynamic technique that can be applied to this problem is known as entropy profiling. Entropy profiles are obtained by monitoring the variation in the open circuit potential as a function of temperature. The peaks in these profiles are related to phase transitions, such as order/disorder transitions, in the lattice. In battery aging studies of cathode materials, the peaks become suppressed but the mechanism by which this occurs is currently poorly understood. One suggested mechanism is the formation of point defects. Intentional modifications of LIB electrodes may also lead to the introduction of point defects. To gain quantitative understanding of the entropy profile changes that could be caused by point defects, we have performed Monte Carlo simulations on lattices of variable defect content. As a model cathode, we have chosen manganese spinel, which has a well-described order-disorder transition when it is half filled with Li. We assume, in the case of trivalent defect substitution (M=Cr,Co) that each defect M permanently pins one Li atom. This assumption is supported by Density Functional Theory (DFT) calculations. Assuming that the distribution of the pinned Li sites is completely random, we observe the same trend in the change in partial molar entropy with defect content as observed in experiment: the peak amplitudes become increasing suppressed as the defect fraction is increased. We also examine changes in the configurational entropy itself, rather than the entropy change, as a function of the defect fraction and analyse these results with respect to the ones expected for an ideal solid solution. We discuss the implications of the quantitative differences between some of the results obtained from the model and the experimentally observed ones.
Sodium‐ion batteries (NIBs) utilize cheaper materials than lithium‐ion batteries (LIBs) and can thus be used in larger scale applications. The preferred anode material is hard carbon, because sodium cannot be inserted into graphite. We apply experimental entropy profiling (EP), where the cell temperature is changed under open circuit conditions. EP has been used to characterize LIBs; here, we demonstrate the first application of EP to any NIB material. The voltage versus sodiation fraction curves (voltage profiles) of hard carbon lack clear features, consisting only of a slope and a plateau, making it difficult to clarify the structural features of hard carbon that could optimize cell performance. We find additional features through EP that are masked in the voltage profiles. We fit lattice gas models of hard carbon sodiation to experimental EP and system enthalpy, obtaining: 1. a theoretical maximum capacity, 2. interlayer versus pore filled sodium with state of charge.
We report on the first year of calendar ageing of commercial high‐energy 21700 lithium‐ion cells, varying over eight state of charge (SoC) and three temperature values. Lithium‐nickel‐cobalt‐aluminium oxide (NCA) and graphite with silicon suboxide (Gr‐SiOx) form cathodes and anodes of those cells, respectively. Degradation is fastest for cells at 70–80 % SoC according to monthly electrochemical check‐up tests. Cells kept at 100 % SoC do not show the fastest capacity fade but develop internal short circuits for temperatures T≥40 °C. Degradation is slowest for cells stored close to 0 % SoC at all temperatures. Rates of capacity fade and their temperature dependencies are distinctly different for SoC values below and above 60 %, respectively. Differential voltage analyses, apparent activation energy analysis, and endpoint slippage tracking provide useful insights into the degradation mechanisms and the respective roles of anode and cathode potential. We discuss how reversible losses of lithium might play a role in alleviating the rate of irreversible losses on commercial cells.
The interface between the electrolyte and graphite anodes plays an important role for lithium (Li) intercalation and has significant impact on the charging/discharging performance of Lithium-Ion Batteries (LIBs).
The effect of temperature on the kinetics of electrochemical insertion/removal of lithium in graphite is analyzed by kinetic Monte Carlo methods. Different electrochemical techniques are simulated at different temperatures and responses are compared with experimental results. Simulated voltammograms show, similarly to experiment, how the behavior of the system becomes closer to equilibrium as temperature increases. Calculated chronoamperometric profiles show a different qualitative behavior in the current at different temperatures, especially in the Cottrell representation peaks, explained in terms of the relative importance of diffusive versus charge transfer processes at different temperatures. Results at room temperature are in good agreement with experiment, and we further evaluate trends at elevated temperature that have not yet been described in experimental or theoretical works. Exchange current densities for different degrees of lithium intercalation at different temperatures are predicted using potentiostatic simulations, showing an Arrhenius-type relationship. The dependence of the exchange current on electrolyte composition is simulated by investigating the effect of different activation energy barriers at different temperatures. The influence of temperature on diffusion coefficients as a function of lithiation fraction in graphite is simulated and related to Arrhenius plots, explaining the experimentally observed changes in diffusion phenomena with lithium composition and temperature.
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