Spin echo Fourier transform proton n.m.r. spectra of whole blood contain resonances from both erythrocytes and plasma. A large number of well-resolved signals from mobile protons of low-molecular-weight metabolites in plasma and serum have been identified. Spectra from the plasmas of eight animal species and commercial, quality control sera are compared. CaEDTA2- and MgEDTA2- resonances can be used for the simultaneous determination of EDTA-chelatable calcium and magnesium concentrations in intact plasma and other biological fluids. Cholesterol is too immobile to contribute to the spectra of intact plasma, but is readily estimated by n.m.r. in both its free and esterified forms after extraction into methanol.

A linear theory of wave propagation in saturated, unconsolidated granular materials, including marine sediments, is developed in this article. Since the grains are unbonded, it is assumed that the shear rigidity modulus of the medium is zero, implying the absence of a skeletal elastic frame. The analysis is based on two types of shearing, translational and radial, which occur at grain contacts during the passage of a wave. These shearing processes act as stress-relaxation mechanisms, which tend to return the material to equilibrium after the application of a dynamic strain. The stress arising from shearing is represented as a random stick-slip process, consisting of a random succession of deterministic stress pulses. Each pulse is produced when micro-asperities on opposite surfaces of a contact slide against each other. The quantity relevant to wave propagation is the average stress from all the micro-sliding events, which is shown to be a temporal convolution between the deterministic stress, h(t), from a single event and the probability, q(t), of an event occurring between times t and t+dt. This probability is proportional to the velocity gradient normal to the tangent plane of contact between grains. The pulse shape function, h(t), is derived by treating the micro-sliding as a strain-hardening process, which yields an inverse-fractional-power-law dependence on time. Based on two convolutions, one for the stress relaxation from translational and the other from radial shearing, the Navier–Stokes equation for the granular medium is derived. In a standard way, it is split into two equations representing compressional and shear wave propagation. From these wave equations, algebraic expressions are derived for the wave speeds and attenuations as functions of the porosity and frequency. Both wave speeds exhibit weak, near-logarithmic dispersion, and the attenuations scale essentially as the first power of frequency. A test of the theory shows that it is consistent with wave speed and attenuation data acquired recently from a sandy sediment in the Gulf of Mexico during the SAX99 experiment. If dispersion is neglected, the predicted expressions for the wave speeds reduce to forms which are exactly the same as those in the empirical elastic model of a sediment proposed by Hamilton. On this basis, the concept of a “skeletal elastic frame” is interpreted as an approximate, but not equivalent, representation of the rigidity introduced by grain-to-grain interactions.

According to a recently developed theory of wave propagation in marine sediments, the dispersion relationships for the phase speed and attenuation of the compressional and the shear wave depend on only three macroscopic physical variables: porosity, grain size, and depth in the sediment. The dispersion relations also involve three (real) parameters, assigned fixed values, representing microscopic processes occurring at grain contacts. The dispersion relationships are compared with extensive data sets, taken from the literature, covering the four wave properties as functions of all three physical variables. With no adjustable parameters available, the theory matches accurately the trends of all the data sets. This agreement extends to the compressional and shear attenuations, in that the theory accurately traces out the lower bound to the widely distributed measured attenuations: the theory predicts the intrinsic attenuation, arising from the irreversible conversion of wave energy into heat, whereas the measurements return the effective attenuation, which includes the intrinsic attenuation plus additional sources of loss such as scattering from shell fragments and other inhomogeneities in the medium. Provided one wave or physical property is known, say the compressional speed or the porosity, all the remaining sediment properties may be reliably estimated from the theory.