Despite their great promise, small experimental thermophotovoltaic (TPV) systems at 1000 K generally exhibit extremely low power conversion efficiencies (approximately 1%), due to heat losses such as thermal emission of undesirable mid-wavelength infrared radiation. Photonic crystals (PhC) have the potential to strongly suppress such losses. However, PhC-based designs present a set of non-convex optimization problems requiring efficient objective function evaluation and global optimization algorithms. Both are applied to two example systems: improved micro-TPV generators and solar thermal TPV systems. Micro-TPV reactors experience up to a 27-fold increase in their efficiency and power output; solar thermal TPV systems see an even greater 45-fold increase in their efficiency (exceeding the Shockley-Quiesser limit for a single-junction photovoltaic cell).

The nascent field of high-temperature nanophotonics could potentially enable many important solid-state energy conversion applications, such as thermophotovoltaic energy generation, selective solar absorption, and selective emission of light. However, special challenges arise when trying to design nanophotonic materials with precisely tailored optical properties that can operate at hightemperatures (>1,100 K). These include proper material selection and purity to prevent melting, evaporation, or chemical reactions; severe minimization of any material interfaces to prevent thermomechanical problems such as delamination; robust performance in the presence of surface diffusion; and long-range geometric precision over large areas with severe minimization of very small feature sizes to maintain structural stability. Here we report an approach for high-temperature nanophotonics that surmounts all of these difficulties. It consists of an analytical and computationally guided design involving high-purity tungsten in a precisely fabricated photonic crystal slab geometry (specifically chosen to eliminate interfaces arising from layer-by-layer fabrication) optimized for high performance and robustness in the presence of roughness, fabrication errors, and surface diffusion. It offers nearultimate short-wavelength emittance and low, ultra-broadband long-wavelength emittance, along with a sharp cutoff offering 4∶1 emittance contrast over 10% wavelength separation. This is achieved via Q-matching, whereby the absorptive and radiative rates of the photonic crystal's cavity resonances are matched. Strong angular emission selectivity is also observed, with shortwavelength emission suppressed by 50% at 75°compared to normal incidence. Finally, a precise high-temperature measurement technique is developed to confirm that emission at 1,225 K can be primarily confined to wavelengths shorter than the cutoff wavelength. E ver since photonic bandgaps were predicted to exist in appropriately designed periodic subwavelength structures (1-3)-i.e., photonic crystals (PhCs), significant interest has garnered in recent years to exploit this property. Coupled with the recent advancements in nanofabrication techniques, many applications have been made possible, ranging from room-and cryogenic-temperature optoelectronic devices for development of all-optical integrated circuits (4), to highly sensitive sensors (5), low-threshold lasers (6), and highly efficient light emitting diodes (7). PhCs also enable us to accurately control spontaneous emission by virtue of controlling the photonic bandgap (1, 8). In particular, metallic PhCs have been shown to possess a large bandgap (9-12) and consequently superior modification of the intrinsic thermal emission spectra is readily achievable. This is extremely promising for many unique applications, especially high-efficiency energy conversion systems encompassing hydrocarbon and radioisotope fueled thermophotovoltaic (TPV) energy conversion (13,14) as well as solar selective absorbers and emitters for the...

We develop a model for predicting the thermal emission spectrum of a 2D metallic photonic crystal for arbitrary angles based on coupled-mode theory. Calculating the appropriate coupled-mode parameters over a range of geometrical parameters allows one to tailor the emissivity spectrum to a specific application. As an example, we design an emitter with a step-function cutoff suppressing long-wavelength emission, which is necessary for high-efficiency thermophotovoltaic systems. We also confirm the accuracy of the results of our model with finite-difference time-domain simulations.

Thermophotovoltaic (TPV) systems are promising for harnessing solar energy, waste heat, and heat from radioisotope decay or fuel combustion. TPV systems work by heating an emitter that emits light that is converted to electricity. One of the key challenges is designing an emitter that not only preferentially emits light in certain wavelength ranges but also simultaneously satisfies other engineering constraints. To elucidate these engineering constraints, we first provide an overview of the state of the art, by classifying emitters into three categories based on whether they have been used in prototype system demonstrations, fabricated and measured, or simulated. We then present a systematic approach for assessing emitters. This consists of five metrics: optical performance, ability to scale to large areas, stability at high temperatures, ability to integrate into the system, and cost. Using these metrics, we evaluate and discuss the reported results of emitters used in system demonstrations. Although there are many emitters with good optical performance, more studies on their practical attributes are required, especially for those that are not yet used in prototype systems. This framework can serve as a guide for the development of emitters for long-lasting, high-performance TPV systems.

vectors R 1 = a͑0,1/ ͱ 2,1/ ͱ 2͒, R 2 = a͑1/ ͱ 2,0,1/ ͱ 2͒ , R 3 = a͑1/ ͱ 2,1/ ͱ 2,0͒, and basis sphere positions, 0, 0.5R 1 , APPLIED PHYSICS LETTERS 88, 241920 ͑2006͒