The magnetic and magnetostriction properties of Z-type cobalt-doped barium hexaferrite with perpendicular c-axis crystallographic texture are presented. The hexaferrite was utilized as a component in Co 2 Z/lead magnesium niobate-lead titanate multiferroic heterostructures whose tunability of permeability with electric field in terms of ferromagnetic resonance shift was supported by experiments and theoretical calculation. A permeability change of 16% was measured by an induced magnetic field of 38 Oe under the application of 6 kV/cm of electric field. These findings lay the foundation for the application of Z-type hexaferrites in tunable rf and microwave devices valued for sending, receiving, and manipulating electromagnetic signals.

Hexagonal barium ferrite (BaFe12O19) thin films were grown at the atomic scale by alternating target laser ablation deposition (ATLAD) of orthorhombic BaFe2O4 and rhombohedral α-Fe2O3 on ⟨00l⟩ Al2O3 substrates. Crystallographic, magnetic, and microwave properties of the ATLAD films were determined to be comparable with single crystal quality bulk and films of BaFe12O19 produced by other techniques. The ability to deposit high quality hexagonal ferrite thin films by utilizing multiple targets of different chemical compositions in the deposition routine provides unique opportunities to control the ionic distribution in the unit cell of this important class of ferrite materials.

The synthesis and properties of Mg((x))Zn((1 - x))Fe(2)O(4) spinel ferrites as a low-toxicity alternative to the technologically significant Ni((x))Zn((1 - x))Fe(2)O(4) ferrites are reported. Ferrite nanoparticles have been formed through both the polyol and aqueous co-precipitation methods that can be readily adapted to industrial scale synthesis to satisfy the demand of a variety of commercial applications. The structure, morphology and magnetic properties of Mg((x))Zn((1 - x))Fe(2)O(4) were studied as a function of composition and particle size. Scanning electron microscopy images show particles synthesised by the aqueous co-precipitation method possess a broad size distribution (i.e. ∼ 80-120 nm) with an average diameter of the order of 100 nm ± 20 nm and could be produced in high process yields of up to 25 g l(-1). In contrast, particles synthesised by the polyol-based co-precipitation method possess a narrower size distribution with an average diameter in the 30 nm ± 5 nm range but are limited to smaller yields of ∼ 6 g l(-1). Furthermore, the polyol synthesis method was shown to control average particle size by varying the length of the glycol surfactant chain. Particles prepared by both methods are compared with respect to their phase purity, crystal structure, morphology, magnetic properties and microwave properties.

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