Glass fibres with silicon cores have emerged as a versatile platform for all-optical processing, sensing and microscale optoelectronic devices. Using SiGe in the core extends the accessible wavelength range and potential optical functionality because the bandgap and optical properties can be tuned by changing the composition. However, silicon and germanium segregate unevenly during non-equilibrium solidification, presenting new fabrication challenges, and requiring detailed studies of the alloy crystallization dynamics in the fibre geometry. We report the fabrication of SiGe-core optical fibres, and the use of CO 2 laser irradiation to heat the glass cladding and recrystallize the core, improving optical transmission. We observe the ramifications of the classic models of solidification at the microscale, and demonstrate suppression of constitutional undercooling at high solidification velocities. Tailoring the recrystallization conditions allows formation of long single crystals with uniform composition, as well as fabrication of compositional microstructures, such as gratings, within the fibre core.
Reduced losses in silicon‐core fibers are obtained using CO2 laser directional recrystallization of the core. Single crystals with aspect ratios up to 1500:1 are reported, limited by the scan range of the equipment. This processing technique holds promise for bringing crystalline silicon‐core fibers to a central role in nonlinear optics and signal processing applications.
Molten alloys under high pressure were used to obtain fibers with long internal electrodes that are solid at room temperature. An integrated Mach-Zehnder interferometer was constructed from a twin-core twin-hole fiber that permitted application of an electric field preferentially to one of the cores. Good stability and a switching voltage of 1.4kV were measured with a 1-m-long fiber device with a quadratic voltage dependence.
Strong grating formation in pure silica-core fibers by use of 193-nm ArF-laser radiation is reported. Unsaturated refractive-index changes of Dn~0.3x10(-3) were observed in nontreated fiber, and changes of Dn~0.5x10(-3) were observed in fibers with a high hydroxyl concentration. Possible mechanisms of photosensitivity in pure silica-core fibers are discussed.
A model based on diffusion of dopants in a periodic structure has been applied to describe thermal decay of chemical composition gratings in fluorine-germanium-doped silica fibers. The good agreement between previously reported values and the diffusion coefficients derived here from experiments and models in the 1000-1200 degrees C temperature range indicate that fluorine diffusion is the main mechanism of grating decay. Experimental results also indicate that the presence of phosphorous significantly increases the decay rate of chemical composition gratings.
Fibre Bragg gratings (FBGs) of type I and IIA were fabricated in Ge-doped and B-Ge co-doped fibres using a 248 nm excimer laser and their performance characteristics were tested and compared with those of a chemical composition grating (CCG), written in a fluorine-germanium doped fibre, over a wide range of temperatures. Long-term testing (more than 600 h) involving a series of step-wise incremental temperature changes shows for the first time the potential of FBGs for high temperature measurement applications (up to and beyond 1100 • C), this depending on the type of FBG involved and the material and composition of the substrate fibre (the CCG was observed to be the most durable at very high temperatures). These gratings are likely to be useful for the simultaneous measurement of strain and temperature over these higher temperature ranges.
Semiconductor core fibers have numerous potential applications in optoelectronics and photonics, and the key to realizing these opportunities is controlled processing of the material. We present results on laser treatments for manipulating the core structure as well as the glass cladding. More specifically, using quasi-CW 10.6 µm radiation, the clad glass can be softened and the core can be controllably melted. This is shown to permit tapering, localized formation of optical resonators, and stress modification of the as-drawn fiber and structures within it. Shown for the first time to the authors' knowledge are Bragg gratings written by modification of the silicon/glass interface using fs laser illumination at 517 nm. The cores of these fibers show stress alterations, with indications of quasi-periodic stress relief in the glass.
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