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Lignocellulosic byproducts derived from biofuel processes were analyzed as functional fillers in polypropylene-based biocomposites. Corn cob, a byproduct yielded from corn harvesting for ethanol production, and sunflower hull, a byproduct of seed stripping for biodiesel production, were both examined as ground filler agents. Composite blends with these lignocellulosic fillers at four filler loadings and four variants of surface compatibilizer loading were melt-compounded using a twin screw extruder and injection molded into test specimens. Tensile testing, notched Izod impact testing, and thermal-mechanical analysis were performed on the composites. The role of filler type, loading, and surface compatibilization were established and reported. Additionally, elastic modulus and tensile strength were successfully modeled using established particulate composite models.

Melt mixing in an extruder with polymers is an effective approach for forming nanocomposites, allowing mass production applications. The intent of this study is to investigate carbon nanofiber composites with ultrahigh molecular weight polyethylene (UHMWPE) matrix using the twin-screw extruder. To decrease the high viscosity of UHMWPE, a low density polyethylene (LDPE) was added into the UHMWPE. The effects of carbon nanofibers (CNFs) on the crystalline structures and properties of the nanocomposites were analyzed. The differential scanning calorimetry (DSC) and X-ray diffraction (XRD) measurements showed the addition of CNFs decreases the degree of crystallinity, but does not impart significant effects on the crystalline structure of the UHMWPE/LDPE blend. Tensile test results showed that the nanocomposite with loading of 3 wt % CNFs had an increase of 38% in tensile strength and 15% in modulus. The thermal stability and thermal conductivity of UHMWPE/ LDPE blends were also enhanced by the addition of CNFs.