Wearing surgical masks is one of
the best protective measures to
protect humans from viral invasion during the 2019 coronavirus (COVID-19)
outbreak. However, wearing surgical masks for extended periods will
cause uncomfortable sweltering sense to users and are easy to breed
bacteria. Here, we reported a novel fibrous membrane with outstanding
comfortability and antibacterial activity prepared by PP ultrafine
fiber nonwovens and antibacterial functionalized h-BN nanoparticles
(QAC/h-BN). The thermal conductivity of commercial PP nonwovens was
only 0.13 W m–1 K–1, but that
of the QAC/h-BN/PP nanocomposite fibrous membranes can reach 0.88
W m–1 K–1, an enhancement of 706.5%
than commercial PP nonwovens. The surface temperature of commercial
PP surgical masks was 31.8 °C when the wearing time was 60 min.
In contrast, QAC/h-BN/PP surgical masks can reach 33.6 °C at
the same tested time, exhibiting stronger heat dissipation than commercial
PP surgical masks. Besides, the antibacterial rates of QAC/h-BN/PP
nanocomposite fibrous membranes were 99.3% for E. coli and 96.1% for S. aureus, and their
antibacterial mechanism was based on “contact killing”
without the release of unfavorable biocides. We think that the QAC/h-BN/PP
nanocomposite fibrous membranes could provide better protection to
people.
Over 359 million tons of plastics were produced worldwide in 2018, with significant growth expected in the near future, resulting in the global challenge of end-of-life management. The recent identification of enzymes that degrade plastics previously considered non-biodegradable opens up opportunities to steer the plastic recycling industry into the realm of biotechnology.Here, we present the sequential conversion of polyethylene terephthalate (PET) into two types of bioplastics: a medium chain-length polyhydroxyalkanoate (PHA) and a novel bio-based poly(amide urethane) (bio-PU). PET films were hydrolyzed by a thermostable polyester hydrolase yielding 100% terephthalate and ethylene glycol. A terephthalate-degradingPseudomonas was evolved to also metabolize ethylene glycol and subsequently produced PHA.The strain was further modified to secrete hydroxyalkanoyloxy-alkanoates (HAAs), which were used as monomers for the chemo-catalytic synthesis of bio-PU. In short, we present a novel value-chain for PET upcycling, adding technological flexibility to the global challenge of endof-life management of plastics.
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