Two-dimensional (2D) materials have attracted tremendous research interest since the breakthrough of graphene. Their unique optical, electronic, and mechanical properties hold great potential for harnessing them as key components in novel applications for electronics and optoelectronics. Their atomic thickness and exposed huge surface even make them highly designable and manipulable, leading to the extensive application potentials. What's more, after acquiring the qualification for being the candidate for next-generation devices, the assembly of 2D materials monomers into mass or ordered structure is also of great importance, which will determine their ultimate industrialization. By designing the monomers and regulating their assembling behavior, the exploration of 2D materials toward the next-generation circuits can be spectacularly achieved. In this review, we will first overview the emerging 2D materials and then offer a clear guideline of varied physical and chemical strategies for tuning their properties. Furthermore, assembly strategies of 2D materials will also be included. Finally, challenges and outlooks in this promising field are featured on the basis of its current progress.
Two-dimensional (2D) gallium nitride (GaN) has been highly anticipated because its quantum confinement effect enables desirable deep-ultraviolet emission, excitonic effect and electronic transport properties. However, the currently obtained 2D GaN can only exist as intercalated layers of atomically thin quantum wells or nanometer-scale islands, limiting further exploration of its intrinsic characteristics. Here, we report, for the first time, the growth of micrometer-sized 2D GaN single crystals on liquid metals via a surface-confined nitridation reaction and demonstrate that the 2D GaN shows uniformly incremental lattice, unique phonon modes, blue-shifted photoluminescence emission and improved internal quantum efficiency, providing direct evidence to the previous theoretical predictions. The as-grown 2D GaN exhibits an electronic mobility of 160 cm 2 •V −1 •s −1 . These findings pave the way to potential optoelectronic applications of 2D GaN single crystals.
The challenges facing the rapid developments of highly integrated electronics, photonics, and microelectromechanical systems suggest that effective fabrication technologies are urgently needed to produce ordered structures using components with high performance potential. Inspired by the spontaneous organization of molecular units into ordered structures by noncovalent interactions, we succeed for the first time in synthesizing a two-dimensional superordered structure (2DSOS). As demonstrated by graphene, the 2DSOS was prepared via self-assembly of high-quality graphene single crystals under mutual electrostatic force between the adjacent crystals assisted by airflow-induced hydrodynamic forces at the liquid metal surface. The as-obtained 2DSOS exhibits tunable periodicity in the crystal space and outstanding uniformity in size and orientation. Moreover, the intrinsic property of each building block is preserved. With simplicity, scalability, and continuously adjustable feature size, the presented approach may open new territory for the precise assembly of 2D atomic crystals and facilitate its application in structurally derived integrated systems.
High‐entropy alloys (HEAs) are based on five or more principal elements with equal or nearly equal molar fractions and possess many significant advantages over traditional alloys, including high strength and hardness, excellent corrosion resistance, outstanding thermal stability, and irradiation resistance. Phase structure plays a vital role in determining the property of HEAs. For further enhancing the performance of HEAs in various application fields, a controllable synthesis with desired phases is required. In this review, the diverse phase structures of HEAs and the related properties are first introduced. Then, alternative tuning strategies to promote the desired phase structure of HEAs are focused upon. Property adjusting of phase‐engineered HEAs is also discussed in depth. Lastly, some insights into the challenges and future prospects in this rapidly emerging research field are provided.
The self-limited chemical vapor deposition of uniform single-layer graphene on Cu foils generated significant interest when it was initially discovered. Soon after, the fabrication of real uniform graphene was found to need extremely precise control of the growth conditions. Slight deviations terminate the self-limiting homogeneous growth, inevitably leading to multilayer graphene formation. Here we propose an innovative way to utilize liquid metals to resolve this thorny problem. In stark contrast to the low carbon solubility found in solid metals (e.g., Cu), catalytically decomposed carbon atoms are embedded in liquid metals. During cooling, the homogeneous solidified surface forms from the quasi-atomic smooth liquid surface, and carbon precipitation is blocked by the frozen metal lattices, which are insoluble to carbon. The underlying liquid bulk acts as a container to buffer the excess carbon supply, which normally would lead to the formation of multilayer graphene in the conventional CVD process. As a result, the growth of graphene becomes governed by a self-limiting surface catalytic process and is robust to variations in growth conditions. With simplicity, scalability, and a large growth window, the use of liquid metals provides an attractive solution to obtain uniform graphene.
Lanthanide (Ln) group elements have been attracting considerable attention owing to the distinct optical properties. The crystal-field surroundings of Ln ions in the host materials can determine their energy level splitting, which is of vital importance to tailor their optical properties. 2D MoS single crystals were utilized as the host material to embed Eu and energy-level splitting was achieved for tuning its photoluminescence (PL). The high anisotropy of the 2D host materials makes them distort the degenerate orbitals of the Ln ions more efficiently than the symmetrical bulk host materials. A significant red-shift of the PL peak for Eu was observed. The strategy for tailoring the energy level splitting of Ln ions by the highly designable 2D material crystal field provides a new method to extend their optical properties.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.