We report that freestanding films of vertically aligned carbon nanotubes exhibit super-compressible foamlike behavior. Under compression, the nanotubes collectively form zigzag buckles that can fully unfold to their original length upon load release. Compared with conventional low-density flexible foams, the nanotube films show much higher compressive strength, recovery rate, and sag factor, and the open-cell nature of the nanotube arrays gives excellent breathability. The nanotube films present a class of open-cell foam structures, consisting of well-arranged one-dimensional units (nanotube struts). The lightweight, highly resilient nanotube films may be useful as compliant and energy-absorbing coatings.

Traditional fibre-reinforced composite materials with excellent in-plane properties fare poorly when out-of-plane through-thickness properties are important. Composite architectures with fibres designed orthogonal to the two-dimensional (2D) layout in traditional composites could alleviate this weakness in the transverse direction, but all of the efforts so far have only produced limited success. Here, we unveil an approach to the 3D composite challenge, without altering the 2D stack design, on the basis of the concept of interlaminar carbon-nanotube forests that would provide enhanced multifunctional properties along the thickness direction. The carbon-nanotube forests allow the fastening of adjacent plies in the 3D composite. We grow multiwalled carbon nanotubes on the surface of micro-fibre fabric cloth layouts, normal to the fibre lengths, resulting in a 3D effect between plies under loading. These nanotube-coated fabric cloths serve as building blocks for the multilayered 3D composites, with the nanotube forests providing much-needed interlaminar strength and toughness under various loading conditions. For the fabricated 3D composites with nanotube forests, we demonstrate remarkable improvements in the interlaminar fracture toughness, hardness, delamination resistance, in-plane mechanical properties, damping, thermoelastic behaviour, and thermal and electrical conductivities making these structures truly multifunctional.

Nanotechnology V 1505Super-Compressible Foamlike Carbon Nanotube Films. -Freestanding films of vertically aligned, multiwalled carbon nanotubes produced by chemical vapor deposition with ferrocene and xylene as the precursors exhibit super-compressible foamlike behavior. Under compression, the nanotubes collectively form zigzag buckles that can fully unfold to their original length upon load release. The nanotube films show much higher compression strength, recovery rate, and sag factor than conventional low-density flexible foams. The lightweight, highly resilient nanotube films may be useful as compliant and energy-absorbing coatings. -(CAO*, A.; DICKRELL, P. L.; SAWYER, W. G.; GHASEMI-NEJHAD, M. N.; AJAYAN, P. M.; Sci. (Washington, D. C., USA) 310 (2005) 5752, 1307-1310; Dep. Mech. Eng., Univ. Hawaii, Honolulu, HI 96822, USA; Eng.) -W. Pewestorf 09-235

Brushes are common tools for use in industry and our daily life, performing a variety of tasks such as cleaning, scraping, applying and electrical contacts. Typical materials for constructing brush bristles include animal hairs, synthetic polymer fibres and metal wires (see, for example, ref. 1). The performance of these bristles has been limited by the oxidation and degradation of metal wires, poor strength of natural hairs, and low thermal stability of synthetic fibres. Carbon nanotubes, having a typical one-dimensional nanostructure, have excellent mechanical properties, such as high modulus and strength, high elasticity and resilience, thermal conductivity and large surface area (50-200 m2 g(-1)). Here we construct multifunctional, conductive brushes with carbon nanotube bristles grafted on fibre handles, and demonstrate their several unique tasks such as cleaning of nanoparticles from narrow spaces, coating of the inside of holes, selective chemical adsorption, and as movable electromechanical brush contacts and switches. The nanotube bristles can also be chemically functionalized for selective removal of heavy metal ions.

In this paper, two different approaches for modeling the behaviour of carbon nanotubes are presented. The first method models carbon nanotubes as an inhomogeneous cylindrical network shell using the asymptotic homogenization method. Explicit formulae are derived representing Young's and shear moduli of single-walled nanotubes in terms of pertinent material and geometric parameters. As an example, assuming certain values for these parameters, the Young's modulus was found to be 1.71 TPa, while the shear modulus was 0.32 TPa. The second method is based on finite element models. The inter-atomic interactions due to covalent and non-covalent bonds are replaced by beam and spring elements, respectively, in the structural model. Correlations between classical molecular mechanics and structural mechanics are used to effectively model the physics governing the nanotubes. Finite element models are developed for single-, double-and multi-walled carbon nanotubes. The deformations from the finite element simulations are subsequently used to predict the elastic and shear moduli of the nanotubes. The variation of mechanical properties with tube diameter is investigated for both zig-zag and armchair configurations. Furthermore, the dependence of mechanical properties on the number of nanotubules in multi-walled structures is also examined. Based on the finite element model, the value for the elastic modulus varied from 0.9 to 1.05 TPa for single and 1.32 to 1.58 TPa for double/multi-walled nanotubes. The shear modulus was found to vary from 0.14 to 0.47 TPa for single-walled nanotubes and 0.37 to 0.62 for double/multi-walled nanotubes.

Nanostructured components are introduced in membrane electrodes assembly ͑MEA͒ in proton exchange membrane fuel cell as a solution to improve the performance. Single-walled carbon nanotubes and multiwalled carbon nanotubes supported platinum are used to fabricate the gas diffusion layer ͑GDL͒ and the catalyst layers in the MEAs, respectively. The physicochemical and electrochemical characterizations of these nanotube-based components demonstrate excellent GDL surface morphology and uniform distribution of the platinum catalyst over the carbon nanotube support. The fuel cell testing using these nanostructured components exhibits promising fuel cell performance using hydrogen-air and hydrogen-oxygen at ambient pressure.

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This work presents the manufacturing and testing of active composite panels (ACPs) with embedded piezoelectric sensors and actuators. The composite material employed here is a plain weave carbon/epoxy prepreg fabric with 0.30 mm ply thickness. A cross-ply type stacking sequence is employed for the ACPs. The piezoelectric flexible patches employed here are Active Fiber Composite (AFC) piezoceramics with 0.33 mm thickness. Composite layers with openings are used to fill the space around the embedded piezo patches to minimize the problems associated with ply drops in composites. The AFC piezoceramic patches were embedded inside the composite laminate. High-temperature wires were soldered to the piezo leads, insulated from the carbon substructure by high-temperature materials, and were taken out of the composite laminates employing cutout hole, molded-in hole, and embedding techniques. The laminated ACPs with their embedded piezoelectric sensors and actuators were vacuum bagged and co-cured inside an autoclave employing the cure cycle recommended by the composite material supplier. The Curie temperature of the embedded piezo patches should be well above the curing temperature of the composite materials as was the case here. The capacitance of the piezoelectric patches was measured before and after cure for quality control. The manufactured ACPs were trimmed and then tested for their functionality. A finite element analysis (FEA) model was developed to verify the free expansion of the AFC FEA. Next, the FEA model of the manufactured ACP was developed based on the AFC FEA free expansion model and was employed to test the functionality of the AFCs embedded within the ACPs. Both static and dynamic FEA results of the modeled ACPs showed very good agreements with their corresponding experimental results. Finally, vibration suppression as well as simultaneous vibration suppression and precision positioning tests, using Hybrid Adaptive Control (HAC), were successfully conducted on the manufactured ACP beams and their functionality was further demonstrated. The advantages and disadvantages of ACPs with embedded piezoelectric sensor and actuator patches manufactured employing the abovementioned three wires out techniques are also presented in terms of manufacturing and performance.