In this study, Zonguldak, a Turkish city popular with coal mining, was taken into consideration. Coal was the main source of energy for domestic heating in Zonguldak and tonnes of ash were dumped to environment. The ash samples were containing carbon and this carbon was aimed to recycle from these waste. In the order of this recycling, firstly classification of collected ash samples in terms of size groups was carried out. For each size groups sink and float analysis was carried out. Sink and float analysis was carried out with densities (1.30, 1.45, 1.60, 1.90 g/cm3) for a total of 5 size groups of ash (+18.00mm, -18.00+10.00mm, -10.00+6.00mm, - 6.00+2.36mm, -2.36+0.50mm) and each floated product was analysed in terms of final ash percentage. Size group -18+10 mm was floated at 1.30 g/cm3 and it was observed that this group of coal ash has the highest percentage (%58.84) carbon.
In this study, a total of 12 coal samples were collected. Physical and chemical cleaning were employed on these collected coal samples. In order to understand the effect of physical & chemical cleaning on these samples, samples characterization were performed in terms of proximate and ultimate analysis. Calorific values of each corresponding clean coal samples were also determined. After chemical cleaning calorific values of each sample decreased, while chemical cleaning resulted in ultra clean coals as regards to ash content (average of 0.5 % ash content). Volatile matter content each corresponding sample after chemical cleaning have higher percentage with respect to the ones after physical cleaning. However for some specific sample, the increase in volatile matter content after chemical cleaning is more than 200 %. Fixed carbon percentages do not show tremendous changes as regards to chemical cleaning, however they decrease for some and increase for some other after chemical cleaning. Calorific values decreases for the all samples after chemical cleaning. Ultimate analysis (C, H, N and O) was also determined after physical and chemical cleaning. Sulphur decreased for all samples after chemical cleaning as expected. Taking these variations into consideration, calorific value decrease were deducted and possible reasons of this decrease was inferred. Corresponding differentiations were compared to calorific value differentiation and the most significant reasoning of the calorific value decrease was evaluated.
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