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Multicomponent adsorption of benzene, toluene, ethylbenzene, and xylene (BTEX) was assessed in aqueous solutions by montmorillonite modified with tetradecyl trimethyl ammonium bromide (TTAB-Mt). Batch experiments were conducted to determine the influences of parameters including loading rates of surfactant, contact time, pH, adsorbate concentration, and temperature on the adsorption efficiency. Scanning electron microscope (SEM) and X-ray diffractometer (XRD) were used to determine the adsorbent properties. Results showed that the modification of the adsorbent via the surfactant causes structural changes of the adsorbent. It was found that the optimum adsorption condition achieves with the surfactant loading rate of 200% of the cation exchange capacity (CEC) of the adsorbent for a period of 24 h. The sorption of BTEX by TTAB-Mt was in the order ofB<T<E<X. The experimental data were fitted by many kinetic and isotherm models. The results also showed that the pseudo-second-order kinetic model and Freundlich isotherm model could, respectively, be fitted to the experimental data better than other available kinetic and isotherm models. The thermodynamic study indicated that the sorption of BTEX with TTAB-Mt was achieved spontaneously and the adsorption process was endothermic as well as physical in nature. The regeneration results of the adsorbent also showed that the adsorption capacity of adsorbent after one use was 51% to 70% of original TTAB-Mt.

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Polyvinyl butyral (PVB) was prepared by condensation reaction of butyral with polyvinyl alcohol (PVA) in aqueous phase containing an acid as a catalyst and an emulsifying agent. Properties of the polymer were a function of the relative amounts of the three randomly distributed units of acetal, acetate and vinyl alcohol groups, and the molecular weight. In this work, some effective factors in synthesis of PVB have been investigated by Taguchi method. The percent of the acetalization has been determined according to the ASTM D1396, and the polymer was characterized by IR, TG, and DTG techniques.

Among all the available solutions to the current high energy demand and consequent economic and environmental problems, solar energy, without any doubt, is one of the most promising and widespread solutions. However, conventional solar systems face some intractable challenges affecting their technical performance and economic feasibility. To overcome these challenges, increasing attention has been drawn towards the utilization of heat pipes, as an efficient heat transfer technology, in conventional solar systems. To the authors' knowledge, despite many valuable studies on heat pipe solar collectors (mainly during the last decade), a comprehensive review which surveys and summarizes those studies and identifies the research gaps in this field has not been published to date. This review paper provides an overview of the recent studies on heat pipe solar collectors (HPSCs), their utilization in different domestic, industrial, and innovative applications, challenges, and future research potentials. The concept and principles of HPSCs are first introduced and a review of the previous studies to improve both energy efficiency and cost effectiveness of these collectors is presented. Moreover, a concise section is dedicated to mathematical modeling to demonstrate suitable methods for simulating the performance of HPSCs. Also, the latest applications of HPSCs in water heating, desalination, space heating, and electricity generation systems are reviewed, and finally, some recommendations for future research directions, regarding both development and new applications, are made.

Invention of evacuated tube heat pipe solar collectors (HPSCs) was a huge step forward towards resolving the challenges of conventional solar systems due to their unique features and advantages. This has led to their utilization in a wide range of solar applications surpassing other conventional collectors. However, relatively low thermal efficiency of heat pipe solar (HPS) systems is still the major challenge of solar industry evidenced by numerous studies conducted mainly during the last decade to improve their efficiency. To date, several review papers have been published summarizing studies relevant to utilization of HPSCs in various thermal applications. However, to the authors' knowledge, a comprehensive review which surveys and provides an overview of the studies undertaken to improve the thermal performance of HPS systems (mainly during the last decade) by implementing different strategies has not been published to date. This review paper summarizes all the proposed strategies to improve the thermal efficiency of different industrial, domestic, and innovative HPS systems. First, the concept, structure, and operational principles of HPSCs are introduced concisely. Then, novel structures and designs of HPSCs aiming to increase the thermal efficiency of the collector as the most important component of the solar system is reviewed. This is followed by a comprehensive review of various methods to store solar energy more efficiently, increase solar system's operation time, increase overall efficiency by turning the solar system into a multipurpose system, enhance heat transmission in the solar system, and implement new solar loop and heat pipe working fluids with better heat transfer characteristics. Finally, research gaps in this field are identified and some future research trends and directions are recommended.

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Composites of polyvinylchloride (PVC) with single wall carbon nanotubes (SWCNTs) were prepared by plastisol curing. Scanning electron microscopy (SEM) observations revealed that appropriate dispersion of the nanotubes was achieved. The mechanical properties showed that SWCNT improved the Young's modulus and tensile strength of the PVC. The composites have higher elongation at break and toughness as well. By comparing the mechanical properties of the composites, it is found that there is a critical SWCNT loading (about 1 wt%) below which the tensile properties increase with increasing nanofiller concentration. For the composites containing 0.25–0.75 wt% of SWCNT, this situation was observed, whereas for a sample with 1 wt% SWCNT, the mechanical properties decreased due to the agglomeration of the nanotubes. Thermogravimetric analysis indicated that the SWCNT increased T5%, T10%, T50%, Tonset, and Tmax and decreased weight loss in the degradation process of the PVC. In addition, by adding SWCNT to the polymer, residual mass at 600°C increased significantly. These results are advantages for the applications of the polymer in which high mechanical properties, including high tensile modulus and toughness, and good thermal properties are needed. J. VINYL ADDIT. TECHNOL., 22:128–133, 2016. © 2014 Society of Plastics Engineers