We theoretically study physical properties of the most promising color center candidates for the recently observed single-photon emissions in hexagonal boron nitride (h-BN) monolayers. Through our group theory analysis combined with density functional theory (DFT) calculations we provide several pieces of evidence that the electronic properties of the color centers match the characters of the experimentally observed emitters. We calculate the symmetry-adapted multi-electron wavefunctions of the defects using group theory methods and analyze the spin-orbit and spin-spin interactions in detail. We also identify the radiative and non-radiative transition channels for each color center. An advanced ab initio DFT method is then used to compute energy levels of the color centers and their zero-phonon-line (ZPL) emissions. The computed ZPLs, the profile of excitation and emission dipole polarizations, and the competing relaxation processes are discussed and matched with the observed emission lines. By providing evidence for the relation between single-photon emitters and local defects in h-BN, this work provides the first steps towards harnessing quantum dynamics of these color centers.arXiv:1709.05414v2 [cond-mat.mes-hall]

We describe a reversible quantum interface between an optical and a microwave field using a hybrid device based on their common interaction with a micromechanical resonator in a superconducting circuit. We show that, by employing state-of-the-art optoelectromechanical devices, one can realize an effective source of (bright) two-mode squeezing with an optical idler (signal) and a microwave signal, which can be used for high-fidelity transfer of quantum states between optical and microwave fields by means of continuous variable teleportation.

Recently observed quantum emitters in hexagonal boron nitride (hBN) membranes have a potential for achieving high accessibility and controllability thanks to the lower spatial dimension. Moreover, these objects naturally have a high sensitivity to vibrations of the hosting membrane due to its low mass density and high elasticity modulus. Here, we propose and analyze a spin-mechanical system based on color centers in a suspended hBN mechanical resonator. Through group theoretical analyses and ab initio calculation of the electronic and spin properties of such a system, we identify a spin doublet ground state and demonstrate that a spin-motion interaction can be engineered which enables ground state cooling of the mechanical resonator. We also present a toolbox for initialization, rotation, and readout of the defect spin qubit. As a result the proposed setup presents the possibility for studying a wide range of physics. To illustrate its assets, we show that a fast and noise resilient preparation of a multicomponent cat state and a squeezed state of the mechanical resonator is possible; the latter is achieved by realizing the extremely detuned, ultrastrong coupling regime of the Rabi model, where a phonon superradiant phase transition is expected to occur.