Curriculum mapping is the process of creating a visual representation of the teaching and assessment of learning outcomes in a degree, program or major. Best practice recommendations about curriculum mapping typically focus on mapping individual programs. Therefore, many recommendations, such as meeting individually with faculty as they map their course, may not be feasible for large-scale mapping projects. This paper describes the process of a large-scale curriculum mapping project designed to map the Bachelor of Science degree and 24 of its associated majors. The project involved the participation of faculty from three colleges within a research-intensive University to map over 400 courses. We describe the key questions and decisions involved in carrying out the mapping project, our data collection and analysis process, and our dissemination efforts to ensure that the mapping results were used to inform curricular change.
An experimental and theoretical investigation on the iridium/zinc-co-catalyzed ring-opening reactions of oxabicyclic alkenes with indole nucleophiles is reported. The reaction affords trans-3-indolyl-1,2-dihydronaphthalen-1-ol products in good yield with no N-alkylated products observed. The C−C bond-forming reaction does not require prior functionalization and is entirely atom-economic. The mechanism and origins of selectivity in the iridium-catalyzed ring-opening reaction have been examined at the M06-D3/Def2TZVPP level of theory. Orbital analysis and natural population analysis charges demonstrate that the C α site of the πallyliridium intermediate is the most electrophilic site of attack. Distortion/interaction analysis reveals that the chemoselectivity likely originates from an earlier-stage transition state between C α and C 3 , which requires less distortion energy compared to C α −N 1 during the rate-determining intermolecular nucleophilic attack. Moreover, conceptual density functional theory was used to conceptualize the preferential reactive sites of the nucleophiles probed. The C−C bond-forming step is speculated to proceed through a Friedel−Crafts-type reaction.
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