We report the development of a scalable continuous Taylor vortex reactor for both UV and visible photochemistry. This builds on our recent report (Org. Process Res. Dev. 2017, 21, 1042) detailing a new approach to continuous visible photochemistry. Here we expand this by showing that our approach can also be applied to UV photochemistry and that either UV or visible photochemistry can be scaled-up using our design. We have achieved scale-up in productivity of over 300× with a visible light photo-oxidation that requires oxygen gas and 10× with a UV induced [2+2] cycloaddition obtaining scales of up to 7.45 kg day-1 for the latter. Furthermore, we demonstrate that oxygen is efficiently taken up in to the reactions of singlet O2 and, for the examples examined, that near-stoichiometric quantities of oxygen can be used with little loss of reactor productivity. Furthermore, our design should scalable to substantially larger size as well as having the potential for scaling-out with reactors in parallel.

The paper proposes dimensionless parameters for the analysis of stability in heated channels with supercritical fluids. The parameters are devised basing on the classical phase change and subcooling numbers adopted in the case of boiling channels, proposing a novel formulation making use of fluid properties at the pseudo-critical temperature as a function of pressure. The adopted formulation for dimensionless density of a given fluid provides a unique dependence with respect to dimensionless enthalpy, in a reasonably wide range of system pressures, thus giving generality to the predictions of unstable conditions obtained as a function of dimensionless parameters. It is shown that these parameters allow setting up quantitative stability maps for a single heated channel with imposed overall pressure drop, in analogy with the ones proposed in previous work concerning boiling channels. Similarities with the boiling channel stability phenomena are pointed out, also supporting the conclusions with system code predictions.

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In the lifetime prediction and extension of a nuclear power plant, a reactor pressure vessel (RPV) has to demonstrate the exclusion of brittle fracture. This paper aims to apply fracture mechanics to analyse the non‐uniform cooling effect in case of a loss‐of‐coolant accident on the RPV integrity. A comprehensive framework coupling reactor system, fluid dynamics, fracture mechanics, and probabilistic analyses for the RPVs integrity analysis is proposed. The safety margin of the allowed RTNDT is increased by more than 16°C if a probabilistic method is applied. Considering the non‐uniform plume cooling effect increases KI more than 30%, increases the failure frequency by more than 1 order of magnitude, and increases the crack tip constraint due to the resulting higher stress. Thus, in order to be more realistic and not to be nonconservative, 3D computational fluid dynamics may be required to provide input for the fracture mechanics analysis of the RPV.

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In the present work, a coupled volume-of-fluid (VOF) model with Eulerian thin-film model (ETFM) approach is used to predict the film thickness in an aero-engine bearing chamber. Numerical studies are conducted for a wide range of shaft speeds with lubricant and air flow rates of 100 1/hr and 10 g/s respectively, at a scavenge ratio of 4 on a simplified bearing chamber test rig. Air-flow analysis inside the bearing chamber is also assessed. Primary and secondary airflow predictions are found to be in good agreement with the experimental results. The coupled ETFM+VOF approach is found to be sensitive enough to capture the qualitative trend of oil film formation and distribution over the chamber wall. Oil collection near the sump at a low shaft speed and a rotating oil film at a higher shaft speed are well captured.

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