Reinforcement of rubber by precipitated silica is adversely affected due to lack of strong polymer silica bonding. Functionalized polymers interact strongly with surface silanol groups of precipitated silica. In this work, effect of variation of epoxide content in silica filled Epoxidized Natural Rubber (ENR) compound was studied namely ENR 10, 25, 37.5 and 50mol%. Increasing in epoxide level of rubber has contributed to better rubber filler interaction and lead to better mechanical properties. Meanwhile, ENR’s with greater degree of polarity has contributed significantly to higher storage moduli at small deformation and also leads to increase in bound rubber content value. Fourier transform infrared spectroscopy studies showed that the silanol groups in silica interact with ENR through formation of Si-OH bond.
Abstract. Road surface is designed to be the durable surface material to sustain the traffic loading. However, due to physical and mechanical stress, pavement deterioration is accelerated. Thus, modifying conventional bitumen by improving its properties is seen as the best method to prolong pavement in-service life. The purpose of this paper is to study the effect of waste natural rubber (NR) latex on rheological properties of bitumen. Conventional bitumen PEN 80/100 was modified with different content of waste NR latex using a high shear mixer at temperature of 150°C. The modified binder properties were characterized by conducting physical test (i.e. softening point, penetration and penetration index) and rheological test (i.e. dynamic shear rheometer, DSR). Results showed that, the addition of waste NR latex improved the rheology properties, which indicates by improving of rutting factor (G*/sin δ). This properties improvement has also shows a potential to resist deformation on road surface despite of high traffic loading.
The asphalt binder is modified using natural rubber (NR) based on cup lump to improve its performance and service life due to intense load and weather induced stress. A source of PG 60-70 asphalt was used for preparing a natural rubber modified asphalt, (NRMA). The rheological characteristics of the NRMA was analyzed using dynamic shear rheometer (DSR) according to Superpave test protocol. The presence of the NR also was investigated by thermogravimetric analysis (TGA) and Fouirier infra-red spectroscopy (FTIR). Results showed that the conventional properties of the base bitumen such as penetration, softening point, and temperature susceptibility improved with addition of NR. The DSR analysis exhibited that the presence of elastic NR within the bitumen network increases the viscosity, stiffness and reduces temperature susceptibility which consequently enhances the rutting property.
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