Kinetic uptake experiments on InOF-1 confirm a maximum of 5.42 wt% CO2 capture at 30 o C and a significant 2-fold increase (~11 wt %) in CO2 capture under 20% relative humidity of water vapour. InOF-1 captures CO2 under humidity conditions (10% and 20% RH) and relatively high temperatures (40 and 50 o C) without any degradation of the crystalline structure which was corroborated by PXRD.
NH2-MIL-53(Al) exhibited a considerable stronger affinity to water than MIL-53(Al). Thus, the hydrophobicity (shown by in situ FTIR) of the pores within MIL-53(Al) enhanced the CO2 adsorption.
By kinetic uptake experiments, MIL-53(Al) shows under anhydrous conditions at 30 °C a CO2 capture of 3.5 wt%. When this material is exposed to water vapour (20% RH and 30 °C), there is a considerable 1.5-fold increase in the CO2 capture up to 5.2 wt%.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.