Limited fossil fuel reserves combined with greenhouse gas intensification due to CO2 emissions has encouraged research in renewable fuels. In this work, a flash pyrolysis study of elephant grass cultivars—Pennisetum purpureum Schum cultivar Mott (MEG), P. purpureum Schum cultivar Roxo (REG), and P. purpureum Schum cultivar Capiaçu (CEG)—was carried out. The biomasses were evaluated in terms of energy characterization by proximate and ultimate analysis, thermogravimetric analyses (TG/DTG), X‐ray diffraction (XRD), Fourier transform infrared (FTIR), and analytical pyrolysis (Py‐GC/MS) at 600°C. The characterization results showed that these biomasses have potential for energy applications and to produce valuable chemicals. The pyrolysis products produced were mainly oxygenated, including short‐chain organic acids (C1‐C4), furans, esters, aldehydes, ketone, and phenols. Although the obtained results were similar for the three biomasses with small variations in the yields of the pyrolysis products, the study reveals an important difference in terms of energy density. CEG was proven as the most promising elephant grass cultivar to be applied for fast pyrolysis to obtain bio‐oil due to its higher dry matter production (2115 t km−2), power generated (9529 MWh km−2), HHV (16.22 MJ kg−1), lower ash content (6.75%), higher volatile content (74.84%), and higher carbon content (42.57%).
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Pyrolysis gases can be upgraded through CO2 adsorption. This work shows the pyrolysis of sewage sludge in a 1 kg h−1 rotating cylinder reactor. Non-condensable gases passed through a fixed bed of 13X zeolite at 40 ◦C. Prior to processing actual pyrolysis gases, the equilibrium adsorption capacity of the 13X was evaluated with synthetic CO2 in a magnetic suspension balance to estimate Langmuir, Freundlich and Toth isotherm parameters. Afterwards, a synthetic mixture with composition similar to that of sewage pyrolysis gases was tested in a bench-scale fixed-bed adsorption column to assess both the breakthrough curves for different adsorbent masses (10, 15, and 20 g) and the saturation time of the adsorbent. The dynamic adsorption in the column was modeled as a system of partial differential equations (PDEs), which was transformed into a system of Ordinary Differential Equations (ODEs) via the Method of Lines and, then, solved using DASSL. The ODEs were used to estimate adsorption parameters such as coefficient of axial dispersion, effective diffusivity within the particle, and external coefficient of mass transfer. The synthetic gases were replaced with actual sewage sludge pyrolysis gases in the adsorption column with 13X. The breakthrough curves revealed a quick saturation of the bed by pyrolysis aerosols. Despite its short lifetime in comparison with synthetic gases, the 13X proved effective in adsorbing pyrolysis CO2.
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