Under the right process conditions, nanoparticles can cluster together to form defined, dispersed structures, which can be termed supraparticles. Controlling the size, shape, and morphology of such entities is a central step in various fields of science and technology, ranging from colloid chemistry and soft matter physics to powder technology and pharmaceutical and food sciences. These diverse scientific communities have been investigating formation processes and structure/property relations of such supraparticles under completely different boundary conditions. On the fundamental side, the field is driven by the desire to gain maximum control of the assembly structures using very defined and tailored colloidal building blocks, whereas more applied disciplines focus on optimizing the functional properties from rather ill-defined starting materials. With this review article, we aim to provide a connecting perspective by outlining fundamental principles that govern the formation and functionality of supraparticles. We discuss the formation of supraparticles as a result of colloidal properties interplaying with external process parameters. We then outline how the structure of the supraparticles gives rise to diverse functional properties. They can be a result of the structure itself (emergent properties), of the colocalization of different, functional building blocks, or of coupling between individual particles in close proximity. Taken together, we aim to establish structure-property and process-structure relationships that provide unifying guidelines for the rational design of functional supraparticles with optimized properties. Finally, we aspire to connect the different disciplines by providing a categorized overview of the existing, diverging nomenclature of seemingly similar supraparticle structures.
The maximum magnetisation (saturation magnetisation) obtainable for iron oxide nanoparticles can be increased by doping the nanocrystals with non-magnetic elements such as zinc. Herein, we closely study how only slightly different synthesis approaches towards such doped nanoparticles strongly influence the resulting sub-nano/atomic structure. We compare two co-precipitation approaches, where we only vary the base (NaOH versus NH), and a thermal decomposition route. These methods are the most commonly applied ones for synthesising doped iron oxide nanoparticles. The measurable magnetisation change upon zinc doping is about the same for all systems. However, the sub-nano structure, which we studied with Mössbauer and X-ray absorption near edge spectroscopy, differs tremendously. We found evidence that a much more complex picture has to be drawn regarding what happens upon Zn doping compared to what textbooks tell us about the mechanism. Our work demonstrates that it is crucial to study the obtained structures very precisely when "playing" with the atomic order in iron oxide nanocrystals.
Novel sensor particles have been developed that expand the variety of today's mechanochromic systems. The developed supraparticles consist of several different components to enable the sensor function. First, a luminescence-quenching core material is coated with silica nanoparticles. Second, this structure is surrounded by raspberry-like nanostructured silica particles, which host luminophore moieties. Upon shear stress, components spatially separated in the original supraparticles, namely quencher and luminophore components, come into contact. This causes an irreversible quenching of the luminescence (sensor turn-off ). Different options to select core, quencher, and luminophore components allow to drive the sensors to different sensing options regarding response time, sensitivity, and operation time. The sensors can be sensitive and rapid in response or generated to monitor the influence of shear stress over longer periods of time. Thus, a rapid, visible, "on-the-fly" sensing of shear stress is possible as well as monitoring the impact of prolonged shear stress. The particles are assembled by spray-drying. This affords flexibility when choosing the type of quencher and luminophore moiety. As such, the sensitivity of this robust, particle-based shear stress sensor system can be deliberately configured. Furthermore, the supraparticle sensor can be integrated in surfaces to create interactive, communicating materials.
Herein, a particle system of so‐called raspberry‐like supraparticles, capable of dye removal from water within a few seconds, is presented. These particles are micron sized and assembled of smaller silica nanoparticles as adsorber and iron oxide nanoparticles which act, due to their superparamagnetic properties, as switchable magnets. With this particle design, it is possible to tailor the adsorber structure and adjust the magnetic properties. Using very small silica nanoparticles (10 nm) combined with superparamagnetic iron oxide nanoparticles (10 nm) to build the supraparticles resulted in a system which could clarify a deeply methylene blue dye colored water within 60 seconds via dye adsorption on the particles and their subsequent magnetic separation. A comparison with assembled supraparticles from larger primary nanoparticles revealed the role of the primary nanoparticles to create a porous particle structure which comes with an apparent capillary effect to take up the dye. The system could be regenerated either thermally or by acid treatment and reused consecutively as magnetically recoverable adsorber. Due to the building block principle of the system, modification towards other adsorption tasks should be easily possible. This therefore turns such particle systems into an ideal platform to build tailored adsorbers.
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