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A set 'of ignition data of linear and branched chain alkanes (n-butane, n-pentane, neopentane, . n-heptane, and isooctane) measured in an original rapid compression machine is provided, It allows a comparison of the ignition conditions of pressure, temperature and equivalence ratio for these hydrocarbons. Detailed mechanisms from different research groups based on a similar generic scheme of hydrocarbon oxidation are tested against the experimental ignition delays. The differences between experimental and modeling results are discussed.

Abstract-Verifying critical numerical software involves the generation of test data for floating-point intensive programs. As the symbolic execution of floating-point computations presents significant difficulties, existing approaches usually resort to random or search-based test data generation. However, without symbolic reasoning, it is almost impossible to generate test inputs that execute many paths with floating-point computations. Moreover, constraint solvers over the reals or the rationals do not handle the rounding errors. In this paper, we present a new version of FPSE, a symbolic evaluator for C program paths, that specifically addresses this problem. The tool solves path conditions containing floating-point computations by using correct and precise projection functions. This version of the tool exploits an essential filtering property based on the representation of floating-point numbers that makes it suitable to generate path-oriented test inputs for complex paths characterized by floating-point intensive computations. The paper reviews the key implementation choices in FPSE and the labeling search heuristics we selected to maximize the benefits of enhanced filtering. Our experimental results show that FPSE can generate correct test inputs for selected paths containing several hundreds of iterations and thousands of executable floating-point statements on a standard machine: this is currently outside the scope of any other symbolicexecution test data generator tool.

Floating-point computations are quickly finding their way in the design of safety-and mission-critical systems, despite the fact that designing floating-point algorithms is significantly more difficult than designing integer algorithms. For this reason, verification and validation of floating-point computations is a hot research topic. An important verification technique, especially in some industrial sectors, is testing. However, generating test data for floating-point intensive programs proved to be a challenging problem. Existing approaches usually resort to random or search-based test data generation, but without symbolic reasoning it is almost impossible to generate test inputs that execute complex paths controlled by floating-point computations.Moreover, as constraint solvers over the reals or the rationals do not natively support the handling of rounding errors, the need arises for efficient constraint solvers over floating-point domains. In this paper, we present and fully justify improved algorithms for the propagation of arithmetic IEEE 754 binary floating-point constraints. The key point of these algorithms is a generalization of an idea by B. Marre and C. Michel that exploits a property of the representation of floating-point numbers.

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