The dynamical and thermodynamic phase stabilities of the stoichiometric compound CrN including different structural and magnetic configurations are comprehensively investigated using a first-principles density-functional-theory (DFT) plus U approach in conjunction with experimental measurements of the thermal expansion. Comparing DFT and DFT+U results with experimental data reveals that the treatment of electron correlations using methods beyond standard DFT is crucial. The non-magnetic face-centered cubic B1-CrN phase is both, elastically and dynamically unstable, even under high pressure, while CrN phases with non-zero local magnetic moments are predicted to be dynamically stable within the framework of the DFT+U scheme. Furthermore, the impact of different treatments for the exchange-correlation
In the Cu-Cr system, the formation of supersaturated solid solutions can be obtained by severe plastic deformation. Energy-dispersive synchrotron diffraction measurements on as-deformed Cu-Cr samples as a function of the applied strain during deformation confirm the formation of supersaturated solid solutions in this usually immiscible system. Due to evaluation of the diffraction data by a newly developed energydispersive RIETVELD-program, lattice parameter and microstructural parameters like domain size and microstrain are determined for as-deformed as well as annealed samples. The obtained information is used to deepen the understanding of the microstructural evolution and the formation of supersaturated solid solutions during severe plastic deformation. Complimentary transmission electron microscopy investigations are furthermore performed to characterize the evolving microstructure in detail. After annealing at elevated temperatures, the formed solid solutions decompose. Compared to the as-deformed state, an enhanced hardness combined with a high thermal stability is observed. Possible mechanisms for the enhanced hardness are discussed.
Published inActa Mater Volume 69 (2014), Pages 301-313 http://dx.
Hard coatings used to protect engineering components from external loads and harsh environments should ideally be strong and tough. Here we study the fracture toughness, K
IC, of Ti1−xAlxN upon annealing by employing micro-fracture experiments on freestanding films. We found that K
IC increases by about 11% when annealing the samples at 900 °C, because the decomposition of the supersaturated matrix leads to the formation of nanometer-sized domains, precipitation of hexagonal-structured B4 AlN (with their significantly larger specific volume), formation of stacking faults, and nano-twins. In contrast, for TiN, where no decomposition processes and formation of nanometer-sized domains can be initiated by an annealing treatment, the fracture toughness K
IC remains roughly constant when annealed above the film deposition temperature. As the increase in K
IC found for Ti1−xAlxN upon annealing is within statistical errors, we carried out complementary cube corner nanoindentation experiments, which clearly show reduced (or even impeded) crack formation for annealed Ti1−xAlxN as compared with their as-deposited counterpart. The ability of Ti1−xAlxN to maintain and even increase the fracture toughness up to high temperatures in combination with the concomitant age hardening effects and excellent oxidation resistance contributes to the success of this type of coatings.
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