The suspension plasma spray (SPS) process was used to produce coatings from yttria-stabilized zirconia (YSZ) powders with median diameters of 15 lm and 80 nm. The powder-ethanol suspensions made with 15-lm diameter YSZ particles formed coatings with microstructures typical of the air plasma spray (APS) process, while suspensions made with 80-nm diameter YSZ powder yielded a coarse columnar microstructure not observed in APS coatings. To explain the formation mechanisms of these different microstructures, a hypothesis is presented which relates the dependence of YSZ droplet flight paths on droplet diameter to variations in deposition behavior. The thermal conductivity (k th ) of columnar SPS coatings was measured as a function of temperature in the as-sprayed condition and after a 50 h, 1200°C heat treatment. Coatings produced from suspensions containing 80 nm YSZ particles at powder concentrations of 2, 8, and 11 wt.% exhibited significantly different k th values. These differences are connected to microstructural variations between the SPS coatings produced by the three suspension formulations. Heat treatment increased the k th of the coatings generated from suspensions containing 2 and 11 wt.% of 80 nm YSZ powder, but this k th increase was less than has been observed in APS coatings.

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The details of fluid flow in tape casting of a Newtonian slurry with a parallel blade are analyzed in terms of the relative magnitudes of the driving forces (wall shear and pressure gradient) and the resulting tape thickness. Prior studies are limited to describe the flow under the blade and within the reservoir. Consideration of the flow after the blade exit indicates that the existence of a zero‐shear plane might have a negative effect on particle alignment in the tape. The more common case of a beveled blade is also analyzed using the one‐dimensional flow model, which is shown to be valid for blade angles up to about 45°. The beveled and parallel blades are compared in terms of productivity, minimum thickness, and potential influence on particle alignment.

A continuum mixture model of the direct chill casting process is compared to experimental results from industrial scale aluminum billets. The model, which includes the transport of free-floating solid particles, can simulate the effect of a grain refiner on macrosegregation and fluid flow. It is applied to an Al-6 wt% Cu alloy and the effect of grain refiner on macrosegregation, sump profile, and temperature fields are presented. Two 45 cm diameter billets were cast under production conditions with and without grain refiner. Temperature and composition measurements and sump profiles are compared to the numerical results. The comparison shows some agreement for the grain refined case. It is believed that an incorrect assumption about the actual grain structure prevents good agreement in the non-grain refined billet.

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