A new material, classified as a soft mixed ionic–electronic conductor (MIEC), was fabricated through casting and curing of different ratios of single walled carbon nanotube (SWNTs), hyaluronic acid (HA), and acrylonitrile butadiene copolymer latex (NBR) and developed for noninvasive stimulation for electrotherapeutics. The morphology of the composite yielded high electrical conductivity and retention of elasticity. The interfacial charge transfer of the material showed that by increasing the HA loading the capacitive contribution decreased, while increasing SWNT loading decreased the interfacial resistance. The soft MIEC materials interfacial charge transfer was superior than current state‐of‐the art electrodes on the market. A layered configuration with high HA ratio at the skin interface and high SWNTs ratio at the stainless‐steel interface was created to induce the most optimal charge transfer. These soft MIEC electrodes will be extremely helpful in electrotherapeutic applications to eliminate the need for hydrogels, which can be unsuitable due the their lack long term durability and instability.

Embedded sensors in footwear are of interest for providing feedback on mobility and gait. The most sensitive location is within the sole, requiring development of new materials that have the required functional and mechanical properties. We are developing capacitive strain sensors. The performance of such sensorsis dictated by two fundamental materials properties: dielectric constant (ε) and hardness. The sensitivity is improved by a high dielectric constant and low hardness. This paper describes a novel material that combines a composite elastomeric polymer and single wall carbon nanotubes (SWCNTs). The optimum SWCNT loading in a polyurethane with 80A shore hardness was determined to be 0.1 vol% which delivered a high SNR and maintained its mechanical properties (hardness). Data collected from a shoe strain sensor array of this material can be used for automatic recognition of postures and activities, for characterization of extremity use, and to provide behavioral enhancing feedback to patients recovering from a stroke.