Electroosmosis is a fascinating effect where liquid motion is induced by an applied electric field. Counter ions accumulate in the vicinity of charged surfaces, triggering a coupling between liquid mass transport and external electric field. In nanofluidic technologies, where surfaces play an exacerbated role, electroosmosis is thus of primary importance. Its consequences on the transport properties in biological and synthetic nanopores are subtle and intricate. Thorough understanding is therefore challenging yet crucial to fully assess the mechanisms at play. Here, we review recent progress on computational techniques for the analysis of electroosmosis and discuss technological applications, in particular for sensing devices.
The last Intergovernmental Panel on Climate Change (IPPC) assessment report highlighted how actions to reduce CO2 emissions have not been effective so far to achieve the 1.5 C limit and that radical measures are required. Solutions such as the upgrading of waste biomass, the power-to-X paradigm, and an innovative energy carrier such as hydrogen can make an effective contribution to the transition toward a low-carbon energy system. In this context, the aim of this study is to improve the hydrogen production process from wet residual biomass by examining the advantages of an innovative integration of anaerobic digestion with thermochemical transformation processes. Furthermore, this solution is integrated into a hybrid power supply composed of an electric grid and a photovoltaic plant (PV), supported by a thermal energy storage (TES) system. Both the performance of the plant and its input energy demand—splitting the power request between the photovoltaic system and the national grid—are carefully assessed by a Simulink/Simscape model. The preliminary evaluation shows that the plant has good performance in terms of hydrogen yields, reaching 5.37% kgH2/kgbiomass, which is significantly higher than the typical value of a single process (approximately 3%). This finding demonstrates a good synergy between the biological and thermochemical biomass valorization routes. Moreover, thermal energy storage significantly improves the conversion plant’s independence, almost halving the energy demand from the grid.
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