Benzo[h]quinoline(bhqH) is metallated with iridium(III) to give [Ir(bhq)2Cl]2 in which bhq is coordinated at 1-N and 10-C atoms. This complex reacts with a ligand(L) such as tri-n-butylphosphine and diethylsulfide to yield [Ir(bhq)2ClL].
Die Umsetzung von Na‐hexahalogenoiridat(III) mit Benzo[h]chinolin führt zu den dimeren Komplexen (I), in denen der Ligand über sein l‐N‐ und sein 10‐C‐Atom zweizähnig gebunden ist.
Two heterotrinuclear complexes, [Mn(II)(Ni(II)L)2].2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [Fe(III)(Ni(II)L)2]NO3.C2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (Ni(II)-Mn(II)) and antiferromagnetic (Ni(II)-Fe(III)).
Cyclo-palladated (dimethylaminomethyl)ferrocene has been resolved into optically pure enantiomers via the (S)-proline derivatives. The absolute configuration is assumed by comparing the circular dichroism spectrum with that of similarly cyclo-palladated (S)-[1-(dimethylamino)ethyl]ferrocene of the known configuration. Several optically active derivatives of the cyclo-palladated (dimethylaminomethyl)ferrocene have been prepared and characterized.
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