No abstract

No abstract

Porphyry copper systems supply about 75% of the world’s copper1. They form above subduction zones and are preferen- tially associated with calc-alkaline magmas1,2. Such magmas result from continuous iron depletion during differentiation, in contrast to tholeiitic magmas that show initial iron enrichment during differentiation3. The formation of calc-alkaline magmas is favoured by high water content and oxygen fugacity4–7. These characteristics, as well as magmatic metal contents, are thought to be imparted in the mantle source by fluids of the subducted slab8–10. Yet this process does not explain why porphyry copper systems preferentially occur in thicker arcs1,2. Here I present a statistical assessment of more than 40,000 published geochemical analyses of magmatic rocks from 23 Quaternary-aged volcanic arcs worldwide. I find that magmas of thicker arcs are systematically more calc-alkaline and more depleted in copper than magmas of thinner arcs. This implies that the missing copper in the former accumulates as copper sulphides within or at the base of thicker arcs. Such copper accumulations are an essential step in forming porphyry systems11–13. These results suggest that the thickness of the overriding plate provides a more important control on magma differentiation than the composition of the mantle source, and can explain the preferential association of porphyry copper systems with calc-alkaline magmas and thicker arcs

Arc magmas originate in subduction zones as partial melts of the mantle, induced by aqueous fluids/melts liberated by the subducted slab. Subsequently, they rise through and evolve within the overriding plate crust. Aside from broadly similar features that distinguish them from magmas of other geodynamic settings (e.g., mid-ocean ridges, intraplate), arc magmas display variably high Sr/Y values. Elucidating the debated origin of high Sr/Y signatures in arc magmas, whether due to mantle-source, slab melting or intracrustal processes, is instrumental for models of crustal growth and ore genesis. Here, using a statistical treatment of >23000 whole rock geochemical data, I show that average Sr/Y values and degree of maturation (MgO depletion at peak Sr/Y values) of 19 out of 22 Pliocene-Quaternary arcs correlate positively with arc thickness. This suggests that crustal thickness exerts a first order control on the Sr/Y variability of arc magmas through the stabilization or destabilization of mineral phases that fractionate Sr (plagioclase) and Y (amphibole ± garnet). In fact, the stability of these mineral phases is function of the pressure at which magma evolves, which depends on crustal thickness. The data presented show also that high Sr/Y Pliocene-Quaternary intermediate-felsic arc rocks have a distinct origin from their Archean counterparts.

No abstract

No abstract

The Palaeozoic to Mesozoic igneous and metamorphic basement rocks exposed in the Mérida Andes of Venezuela and the Santander Massif of Colombia are generally considered to define allochthonous terranes that accreted to the margin of Gondwana during the Ordovician and the Carboniferous. However, terrane sutures have not been identified and there are no published isotopic data that support the existence of separate crustal domains. A general paucity of geochronological data led to published tectonic reconstructions for the evolution of the north- western corner of Gondwana that do not account for the magmatic and metamorphic histories of the basement rocks of the Mérida Andes and the Santander Massif. We present new zircon U–Pb (ICP-MS) data from 52 igneous and metamorphic rocks, which we combine with whole rock geochemical and Pb isotopic data to constrain the tectonic history of the Precambrian to Mesozoic basement of the Mérida Andes and the Santander Massif. These data show that the basement rocks of these massifs are autochthonous to Gondwana and share a similar tectono- magmatic history with the Gondwanan margin of Peru, Chile and Argentina, which evolved during the subduc- tion of oceanic lithosphere of the Iapetus Ocean. The oldest Palaeozoic arc magmatism is recorded at ~500 Ma, and was followed shortly by Barrovian metamorphism. Peak metamorphic conditions at upper amphibolite facies are recorded by anatexis at ~477 Ma and the intrusion of synkinematic granitoids until ~472 Ma. Subsequent retrogression resulted from localised back-arc or intra-arc extension at ~453 Ma, when volcanic tuffs and interfingered sedimentary rocks were deposited over the amphibolite facies basement. Continental arc magmatism dwindled after ~430 Ma and terminated at ~415 Ma, coevally with most of the western margin of Gondwana. After Pangaea amalgamation in the Late Carboniferous to Early Permian, a magmatic arc developed on its western margin at ~ 294 Ma as a result of subduction of oceanic crust of the palaeo-Pacific ocean. Intermittent arc magmatism recorded between ~ 294 and ~ 225 Ma was followed by the onset of the Andean subduction cycle at ~ 213 Ma, in an extensional regime. Extension was accompanied by slab roll-back which led to the migration of the arc axis into the Central Cordillera of Colombia in the Early Jurassic

No abstract