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Exergy analysis of the reciprocating internal combustion (IC) engines is studied by estimating various input and output energy transfer parameters concerning a dead state reference. Exergy terms such as fuel input, work output, cooling, and exhaust gas are measured and are set into the exergy balance equation to determine the amount of loss or destruction. Exergy destructions are found in many forms such as combustion (entropy generation), cylinder wall, friction, mixing, blow-by, and others. These exergy terms have been estimated by considering various factors such as engine type, fuel type, environmental condition, and others. In this article, the different methods employed in estimating these exergy terms have been reviewed. It attempts to make a compendium of these evaluation methods and segregates them under individual exergy terms with necessary descriptions. The fuel input measurement is mostly based on Gibb's free energy and the lower heating value, whereas its higher heating value is used during the fuel exergy calculation on a molar basis. The work output of the engines is estimated either from the crankshaft or by analyzing the cylinder pressure and volume. The exergy transfer with cooling medium and exhaust gas depends on the temperature of gas. The maximum achievable engine performance is quantified by estimating the exergy efficiency. This piece of study will not only provide a plenty of information on exergy evaluation methods of IC engines but will also allow the future researchers to adopt the appropriate one.

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