While experts in various fields discuss the potential of carbon capture and storage (CCS) technologies, the utilization of carbon dioxide as chemical feedstock is also attracting renewed and rapidly growing interest. These approaches do not compete; rather, they are complementary: CCS aims to capture and store huge quantities of carbon dioxide, while the chemical exploitation of carbon dioxide aims to generate value and develop better and more-efficient processes from a limited part of the waste stream. Provided that the overall carbon footprint for the carbon dioxide-based process chain is competitive with conventional chemical production and that the reaction with the carbon dioxide molecule is enabled by the use of appropriate catalysts, carbon dioxide can be a promising carbon source with practically unlimited availability for a range of industrially relevant products. In addition, it can be used as a versatile processing fluid based on its remarkable physicochemical properties.

Capturing CO2 and using it as an alternative carbon feedstock for chemicals, fuels and materials has the potential to reduce both CO2 emissions and fossil resource depletion. To assess the actual environmental benefits of CO2 capture and utilization (CCU), life cycle assessment (LCA) is considered as suitable metric. To enhance the use of LCA of CCU, this tutorial review gives a jargon-free introduction of LCA of CCU directed at LCA novices. Nine particularly important aspects for conducting an LCA of CCU are identified and illustrated with CCU examples. These aspects, phrased as action items, can serve LCA novices as a checklist through all steps in LCA of CCU: from defining the LCA purpose and the system boundaries, over data collection and environmental impact computation, to interpretation and sensitivity analysis of the results. Finally, in the context of CCU, an outlook is given on recent developments in LCA that aim to cover all pillars of sustainability (people, planet, and profit).

A combination of quantum‐chemical and thermochemical calculations leads to the prediction of novel polymorphs of Ta3N5 and WN2. Based on thermochemical data the fugacity of nitrogen at very high pressures is estimated which facilitates a detailed assessment of the synthesis conditions. The modifications of Ta3N5‐II and WN2‐II have metal centers the are eight‐ and nine‐fold coordinate (see picture: red W, green N).