Surface sensitive synchrotron x-ray photoelectron spectroscopy (XPS) and real-time in situ XPS were used to study the thermal stability of the hydroxyl termination and downward band bending on the polar surfaces of ZnO single crystals. On the O-polar face, the position of the Fermi level could be reversibly cycled between the conduction band and the band gap over an energetic distance of approximately 0.8 eV (similar to 1/4 of the band gap) by controlling the surface H coverage using simple ultrahigh vacuum (UHV) heat treatments up to 750 degrees C, dosing with H2O/H-2 and atmospheric exposure. A metallic to semiconductorlike transition in the electronic nature of the O-polar face was observed at an H coverage of approximately 0.9 monolayers. For H coverage less than this, semiconducting (depleted) O-polar surfaces were created that were reasonably stable in UHV conditions. In contrast, the downward band bending on the Zn-polar face was significantly more resilient, and depleted surfaces could not be prepared by heat treatment alone.preprintPeer reviewe
Ni, Ir, Pd, Pt, and silver oxide Schottky contacts were fabricated on the Zn-polar face of hydrothermally grown, bulk ZnO. A relationship was found between the barrier height of the contact and the free energy of formation of its “metal” oxide. This is consistent with the dominating influence of oxygen vacancies (VO) which tend to pin the ZnO Fermi level close to the VO (+2,0) defect level at approximately 0.7eV below the conduction band minimum. Therefore, a key goal in the fabrication of high quality Schottky contacts should be the minimization of oxygen vacancies near the metal-ZnO interface.
The positive ion current collected by cylindrical Langmuir probes has been measured in an RF argon plasma. The current-voltage characteristics were measured using an RF compensation technique whereby the probe was forced to follow the RF fluctuation in the local plasma potential. The I-V curves from probes of different radii and material show an ion current which is always greater than that predicted by the orbital motion theory and that agrees well with the radial motion theory. This is because the ions travel to the probe from a distance which is limited by the vessel geometry or by the collisional mean free path. The role of the possible collisions, ion-ion and ion-neutral, in the ion trajectories is analysed. It is suggested that the criterion for the application of the orbital motion theory should be tested whenever this theory is used for the determination of the charged particle density.
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