We present a new kinetic model describing localized electronic recombination through the excited state of the donor (d) to an acceptor (a) centre in luminescent materials. In contrast to the existing models based on the localized transition model (LTM) of Halperin and Braner (1960 Phys. Rev. 117 408-15) which assumes a fixed d → a tunnelling probability for the entire crystal, our model is based on nearest-neighbour recombination within randomly distributed centres. Such a random distribution can occur through the entire volume or within the defect complexes of the dosimeter, and implies that the tunnelling probability varies with the donor-acceptor (d-a) separation distance. We first develop an 'exact kinetic model' that incorporates this variation in tunnelling probabilities, and evolves both in spatial as well as temporal domains. We then develop a simplified one-dimensional, semi-analytical model that evolves only in the temporal domain. An excellent agreement is observed between thermally and optically stimulated luminescence (TL and OSL) results produced from the two models. In comparison to the first-order kinetic behaviour of the LTM of Halperin and Braner (1960 Phys. Rev. 117 408-15), our model results in a highly asymmetric TL peak; this peak can be understood to derive from a continuum of several first-order TL peaks. Our model also shows an extended power law behaviour for OSL (or prompt luminescence), which is expected from localized recombination mechanisms in materials with random distribution of centres.

Summary Both district heating and solar collector systems have been known and implemented for many years. However, the combination of the two, with solar collectors supplying heat to the district heating network, is relatively new, and no comprehensive review of scientific publications on this topic could be found. Thus, this paper summarizes the literature available on solar district heating and presents the state of the art and real experiences in this field. Given the lack of a generally accepted convention on the classification of solar district heating systems, this paper distinguishes centralized and decentralized solar district heating as well as block heating. For the different technologies, the paper describes commonly adopted control strategies, system configurations, types of installation, and integration. Real‐world examples are also given to provide a more detailed insight into how solar thermal technology can be integrated with district heating. Solar thermal technology combined with thermally driven chillers to provide cooling for cooling networks is also included in this paper. In order for a technology to spread successfully, not only technical but also economic issues need to be tackled. Hence, the paper identifies and describes different types of ownership and financing schemes currently used in this field.

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