Herein, we described the efficient and straightforward synthesis of N-substituted α,α-difluoro-β-aminophosphonates with the use of electrophilic fluorination by Selectfluor®.
The goal of this review is to describe recent advances in metal catalyzed reactions and organocatalysis leading to-monofluoro- , ,-gem-difluoro-or trifluoromethyl phosphonate derivatives with a particular emphasis on introducing chiral centers in these compounds.
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