In terms of an optimum material balance, intermolecular catalytic hydroamination reactions [Eq. (1)] are one of the much discussed atom‐economical processes. The problems of hydroamination have not yet been properly solved; however, recent publications describe some very promising work on the homogeneous catalysis of intermolecular hydroamination reactions with transition metal catalysts. This work is described and discussed herein.
Keywords: Boranes / Cluster compounds / Homogeneous catalysis / Platinum / TinThe synthesis and characterization of two (dppp)Pt complexes with the stannaborate ligand SnB 11 H 11 is described. In the case of the salt [Bu 3 MeN] 2 [(dppp)Pt(SnB 11 H 11 ) 2 ] the structure in the solid state was determined by X-ray crystal structure analysis. As a result of comparative catalysis studies between SnCl 3 and [SnB 11 H 11 ] − -substituted platinum com-
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