Experimental investigation of chemical reactions with full quantum state resolution for all reactants and products has been a long-term challenge. Here we prepare an ultracold few-body quantum state of reactants and demonstrate state-to-state chemistry for the recombination of three spin-polarized ultracold rubidium (Rb) atoms to form a weakly bound Rb molecule. The measured product distribution covers about 90% of the final products, and we are able to discriminate between product states with a level splitting as small as 20 megahertz multiplied by Planck's constant. Furthermore, we formulate propensity rules for the distribution of products, and we develop a theoretical model that predicts many of our experimental observations. The scheme can readily be adapted to other species and opens a door to detailed investigations of inelastic or reactive processes.
Abstract. We demonstrate the implementation of a spin qubit with a single 40 Ca + ion in a micro ion trap. The qubit is encoded in the Zeeman ground state levels m J = +1/2 and m J = −1/2 of the S 1/2 state of the ion. We show sideband cooling close to the vibrational ground state and demonstrate the initialization and readout of the qubit levels with 99.5% efficiency. We employ a Raman transition close to the S 1/2 -P 1/2 resonance for coherent manipulation of the qubit. We observe single qubit rotations with 96% fidelity and gate times below 5µs. Rabi oscillations on the blue motional sideband are used to extract the phonon number distribution. The dynamics of this distribution is analyzed to deduce the trap-induced heating rate of 0.3(1) phonons/ms.
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