Summary Of the various enhanced-oil-recovery (EOR) polymer formulations, newly developed associative polymers show special promise. We investigate pore and pore-network scales because polymer solutions ultimately flow through the pore space of rock to displace oil. We conduct and monitor optically water/oil and polymer-solution/oil displacements in a 2D etched-silicon micromodel. The micromodel has the geometrical and topological characteristics of sandstone. Conventional hydrolyzed-polyacrylamide solutions and newly developed associative-polymer solutions with concentrations ranging from 500 to 2,500 ppm were tested. The crude oil had a viscosity of 450 cp at test conditions. Our results provide new insight regarding the ability of polymer to stabilize multiphase flow. At zero and low polymer concentrations, relatively long and wide fingers of injectant developed, leading to early water break-through and low recoveries. At increased polymer concentration, a much greater number of relatively fine fingers formed. The width-to-length ratio of these fingers was quite small, and the absolute length of fingers decreased. At a larger scale of observation, the displacement front appears to be stabilized; hence, recovery efficiency improved remarkably. Above a concentration of 1,500 ppm, plugging of the micromodel by polymer and lower oil recovery was observed for both polymer types. For tertiary polymer injection that begins at breakthrough of water, the severe fingers resulting from water injection are modified significantly. Fingers become wider and grow in the direction normal to flow as polymer solution replaces water. Apparently, improved sweep efficiency of viscous oils is possible (at this scale of investigation) even after waterflooding. The associative- and conventional-polymer solutions improved oil recovery by approximately the same amount. The associative polymers, however, showed more-stable displacement fronts in comparison to conventional-polymer solutions.

Foam as a gas-mobility control agent is successful in enhanced oil recovery processes. An emerging application of foam is to aid surfactant solution delivery for EOR in heterogeneous porous media. In fractured reservoirs, foam acts as a blocking agent slowing and redirecting the transport of the aqueous phase in high transmissibility fractures. Foam aids the imbibition of foamer/surfactant solution into the matrix blocks so that remaining oil is drained. The design of such foam treatments for fractured media is an important factor for economic as well as recovery success. In this work we investigate the behavior of foam flow in fractures at various foam qualities and liquid and gas velocities. Laboratory experiments with different fracture replicates etched in silicon micromodels were used. Micromodels allow real time observations of flow behavior with a microscope and provide a fracture geometry that is easily replicated. A plain smooth fracture with different apertures (40 μm and 30 μm), a fracture with variable smooth apertures (either 20 μm or 40 μm) arranged in a checkerboard pattern and a constant-aperture fracture with a rough face were used to observe pre-generated foam in terms of texture, pressure drop and flow behavior. Mobility reduction factors for a wide range of foam qualities and flow rates were analyzed. Measured pressure drops increase linearly with an increase in foam quality up to 90%. At qualities greater than 90%, mobility reduction is only slightly reduced further. In general, mobility reduction factors (MRF) of 10-600 times were measured for low to high quality foams, respectively. Additionally video footage of foam at micro and macro scale is used to tie rheology to bubble shape and size. Study results are useful as input for upscaling of the rheology of foam fractures and for ultimate use in reservoir simulations to design effective chemical EOR treatments for fractured media.

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About half of world oil production results from waterflooding. The remaining resources, however, are more viscous and less amenable to waterflood as conventional oil reserves are produced. In offshore and Arctic environments improved methods of cold production for viscous oil are needed because the introduction of heat to thin viscous oil appears to be unlikely. Unfavorable mobility ratio and sweep is modified by use of polymer solutions. Of the various EOR polymer formulations, newly developed associative polymers show special promise. We investigate pore and pore network scales because polymer solutions ultimately flow through the pore space of rock to displace oil. We conduct and monitor optically water/oil and polymer solution/oil displacements in a two-dimensional etched-silicon micromodel. The micromodel has the geometrical and topological characteristics of sandstone. Conventional hydrolyzed polyacrylamide solutions and newly developed associative polymer solutions with concentrations ranging from 500 ppm to 2500 ppm were tested. The crude oil had a viscosity of 210 cP at test conditions. Our results provide new insight regarding the ability of polymer to stabilize multiphase flow. At zero and low polymer concentrations, relatively long and wide fingers of injectant developed, leading to early water breakthrough and low recoveries. At increased polymer concentration, a much greater number of relatively fine fingers formed. The width to length ratio of these fingers was quite small and the absolute length of fingers decreased. At a larger scale of observation, the displacement front appears to be stabilized; hence, recovery efficiency improved remarkably. Above a concentration of 1500 ppm, plugging of the micromodel by polymer and lower oil recovery was observed for both polymer types. For tertiary polymer injection that begins at breakthrough of water, the severe fingers resulting from water injection are modified significantly. Fingers become wider and grow in the direction normal to flow as polymer solution replaces water. Apparently, improved sweep efficiency of viscous oils is possible (at this scale of investigation) even after water flooding. The associative and conventional polymer solutions improved oil recovery by about the same amount. The associative polymers, however, showed more stable fronts in comparison to conventional polymer solutions.

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