We discuss the critical trade-off between the spectral dispersion in the second order nonlinearity d(2) and the linear absorption coefficient for second harmonic generation (SHG) by the mixing of copropagating or counterpropagating fundamental beams in poled polymers. The 4-dimethylamino–4′-nitrostilbene side-chain polymer is used as a specific example. The predictive power of the classical two-level model for SHG is also assessed.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.