Rincon de Parangueo is a Quaternary maar that had a perennial lake until the 1980s. The lake was gradually desiccated as a consequence of drawdown in the Salamanca-Valle de Santiago regional aquifer and now functions as a playa-lake. In contrast with the features observed in other crater-lakes in the region (La Alberca, Cíntora, and San Nicolás), which also dried up at the same time, the bottom of the Rincón crater displays clear evidence of active deformation associated with mass movement of lake sediments towards the depocenter inside the crater. The most conspicuous topographic feature is a 10 -12 m high scarp parallel to the former lake coast. The scarp is produced by an annular shaped normal fault system, down towards the depocenter. Evidence of active mass movement is observed along the topographic scarp. Rotational slides associated with rollover anticlines and local grabens produced by antithetic faults are common on the eastern and northern parts of the scarp. Planar slides with open folds at their base occur at western part of the lake basin.Evaporites (trona, thermonatrite, eitelite, halite, and silvite) are abundant in the playa-lake sediments. Their presence makes us believe that a mass removal process is acting as a consequence of salt dissolution and infiltration of the brine towards the aquifer. This process, probably in conjunction with lake sediment compaction and/or diatreme subsidence, may explain the significantly higher fault displacement rate observed inside the crater ( ≈ 50 cm/year ) in comparison with active faults elsewhere in the Salamanca-Valle de Santiago aquifer ( ≈ 6 cm/year ).Keywords: drawdown, maar, evaporite, stromatolite, landslide.
Resumen
SummaryCopper sulfide is a promising p-type inorganic semiconductor for optoelectronic devices such as solar cells, due its small band gap energy and its electrical properties. In this work nanocrystalline copper sulfide (CuxS), with two stoichiometric ratios (x = 2, 1.8) was obtained by one-pot synthesis at 220, 230, 240 and 260 °C in an organic solvent and amorphous CuxS was obtained in aqueous solution. Nanoparticle-like nucleation centers are formed at lower temperatures (220 °C), mixtures of morphologies (nanorods, nanodisks and nanoprisms) are seen at 230 and 240 °C, in which the nanodisks are predominant, while big hexagonal/prismatic crystals are obtained at 260 °C according to TEM results. A mixture of chalcocite and digenite phases was found at 230 and 240 °C, while a clear transition to a pure digenite phase was seen at 260 °C. The evolution of morphology and transition of phases is consistent to the electrical, optical, and morphological properties of the copper sulfide. In fact, digenite Cu1.8S is less resistive (346 Ω/sq) and has a lower energy band gap (1.6 eV) than chalcocite Cu2S (5.72 × 105 Ω/sq, 1.87 eV). Low resistivity was also obtained in CuxS synthesized in aqueous solution, despite its amorphous structure. All CuxS products could be promising for optoelectronic applications.
Key indicatorsSingle-crystal X-ray study T = 297 K Mean (Co-O) = 0.004 Å R factor = 0.031 wR factor = 0.079 Data-to-parameter ratio = 13.1 For details of how these key indicators were automatically derived from the article, see
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