3D printing technology has an enormous
potential to apply to chemical
engineering education. In this paper, we describe several designs
of 3D printed mesoreactors (Y-shape, T-shape, and Long channel shape)
using the following steps: reactor sketching, CAD modeling, and reactor
printing. With a focus on continuous plug flow mesoreactors (PFRs,
i.d. = 2 mm), fluid mixing phenomena were explored by using a passive
mixing method. The small channel of mesoreactors facilitates the stability
of a laminar flow in the system at low Reynolds number. With changes
in flow rates (0.2 and 4.0 mL/min) and channel geometry (0° and
90° outlet angle), fluid mixing was controlled. Our results provided
that 3D printed mesoreactors can be possibly used in teaching fluid
dynamics, chemical kinetics, and reaction engineering, which are main
courses of the chemical engineering undergraduate program. Furthermore,
the cost of mesoreactor printing was suitable (<$1.00/microreactor)
for education.
Facile synthesis of Pd and Pt nanoparticles supported on the boron nitride nanotubes (Pd-BNNT and Pt-BNNT, respectively) for CO oxidation was explored. The reduction agent and stabilizer-free synthesis solely relies on the ultrasound treatment of the aqueous Pd 2+ and Pt 4+ precursors under the presence of BNNT. Reduction of Pd and Pt nanoparticles on the surface of BNNT was observed by means of the transmission electron microscopy and X-ray diffraction patterns. Quantitative analysis of Pd and Pt attached on the BNNT surface was also carried out using inductively coupled plasma atomic emission spectroscopy, showing that the concentration of metal nanoparticles on BNNT could be controlled by varying the initial concentration of metal precursors and the ultrasound treatment time. The morphological evolution of the nanoparticles on the surface of BNNT was observed by raising the temperature up to 800 °C in an air and up to 900 °C in vacuum. It was found that the nanoparticles were thermally stable up to 600 °C for both cases. The efficiency of catalytic oxidation of CO of the synthesized Pd-BNNT and Pt-BNNT was measured to be higher than ∼98% at the temperature as low as ∼125 and ∼150 °C, respectively.
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