We have demonstrated the solid-state formation of a uranyl peroxide (UP) species from hydrated uranyl fluoride via a uranyl hydroxide intermediate, the first observation of a UP species formed in a solid-state reaction. Water vapor pressure is shown to be a driving factor of both the loss of fluorine and the subsequent formation of peroxo units. We have ruled out a photochemical mechanism for formation of the UP species by demonstrating that the same reaction occurs in the dark. A radiolytic mechanism is unlikely because of the low radioactivity of the sample material, suggesting the existence of a novel UP formation mechanism.
We confirm that synthetic uranyl hydroxide hydrate metaschoepite [(UO)24O(OH)6]·5H2O is unstable against dehydration under dry conditions, and we present a structural and vibrational spectroscopic study of synthetic metaschoepite and its ambient temperature dehydration product. Complementary structural (X-ray diffraction and neutron diffraction) and vibrational spectroscopic techniques (Raman spectroscopy, infrared spectroscopy, and inelastic neutron scattering) are used to probe different components of these species. Analysis of the dehydration product suggests that it contains both pentagonally coordinated and hexagonally coordinated uranyl ions, necessitating that some uranyl ions undergo a coordination change during the dehydration of pentagonally coordinated metaschoepite. Vibrational spectra of metaschoepite and its dehydration product are interpreted with power spectra generated from ab initio molecular dynamics trajectories, allowing assignment of all major features. We identify the uranyl symmetric stretching modes of the four distinct uranyl ions in synthetic metaschoepite and clarify the assignment of lower energy Raman modes in both structures. The coanalysis of experimental and computational data reveals a strong coupling between the uranyl stretching modes and hydroxide bending modes in the anhydrous structure, leading to the presence of several high-energy combination bands in the inelastic neutron scattering data.
Uranyl fluoride (UOF) is a hygroscopic powder with two main structural phases: an anhydrous crystal and a partially hydrated crystal of the same R3¯m symmetry. The formally closed-shell electron structure of anhydrous UOF is amenable to density functional theory calculations. We use density functional perturbation theory (DFPT) to calculate the vibrational frequencies of the anhydrous crystal structure and employ complementary inelastic neutron scattering and temperature-dependent Raman scattering to validate those frequencies. As a model closed-shell actinide, we investigated the effect of LDA, GGA, and non-local vdW functionals as well as the spherically averaged Hubbard +U correction on vibrational frequencies, electronic structure, and geometry of anhydrous UOF. A particular choice of U=5.5 eV yields the correct U-O bond distance and vibrational frequencies for the characteristic E and A modes that are within the resolution of experiment. Inelastic neutron scattering and Raman scattering suggest a degree of water coupling to the lattice vibrations in the more experimentally accessible partially hydrated UOF system, with the symmetric stretching vibration shifted approximately 47 cm lower in energy compared to the anhydrous structure. Evidence of water interaction with the uranyl ion is present from a two-peak decomposition of the uranyl stretching vibration in the Raman spectra and anion-hydrogen stretching vibrations in the inelastic neutron scattering spectra. A first-order dehydration phase transition temperature is definitively identified to be 125 °C using temperature-dependent Raman scattering.
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