In this work, powders of NiSb2O6 were synthesized using a simple and economical microwave-assisted wet chemistry method, and calcined at 700, 800, and 900 °C. It was identified through X-ray diffraction that the oxide is a nanomaterial with a trirutile-type structure and space group P42/mnm (136). UV–Vis spectroscopy measurements showed that the bandgap values were at ~3.10, ~3.14, and ~3.23 eV at 700, 800, and 900 °C, respectively. Using scanning electron microscopy (SEM), irregularly shaped polyhedral microstructures with a size of ~154.78 nm were observed on the entire material’s surface. The particle size was estimated to average ~92.30 nm at the calcination temperature of 900 °C. Sensing tests in static atmospheres containing 300 ppm of CO at 300 °C showed a maximum sensitivity of ~72.67. On the other hand, in dynamic atmospheres at different CO flows and at an operating temperature of 200 °C, changes with time in electrical resistance were recorded, showing a high response, stability, and repeatability, and good sensor efficiency during several operation cycles. The response times were ~2.77 and ~2.10 min to 150 and 200 cm3/min of CO, respectively. Dynamic tests in propane (C3H8) atmospheres revealed that the material improved its response in alternating current signals at two different frequencies (0.1 and 1 kHz). It was also observed that at 360 °C, the ability to detect propane flows increased considerably. As in the case of CO, NiSb2O6’s response in propane atmospheres showed very good thermal stability, efficiency, a high capacity to detect C3H8, and short response and recovery times at both frequencies. Considering the great performance in propane flows, a sensor prototype was developed that modulates the electrical signals at 360 °C, verifying the excellent functionality of NiSb2O6.
<p>Este artículo presenta una alternativa para resolver la vulnerabilidad existente en los sistemas que implementan el enmascaramiento mediante la sincronización caótica, este sistema evita que los parámetros utilizados como clave de cifrado puedan ser detectados por un atacante al implementar el modelo matemático caótico del oscilador de Rössler para codificar y establecer la sincronización entre los dispositivos transmisor-receptor; además usa dos llaves de cifrado: la primera con una longitud recomendable de 2048 caracteres y la segunda se utiliza como un valor inicial. Ambas llaves se emplean para modificar continuamente uno de los parámetros del oscilador, esto fortalece la seguridad del sistema y evita que un atacante obtenga los valores del parámetro del oscilador calculando el error de sincronización promedio menor. El uso del sistema desarrollado proporciona un cifrado resistente a ataques estadísticos, además valida datos del dispositivo transmisor (nombre de usuario, password, etc.) para autorizar la transmisión hacia el destino.</p>
Nanoparticles of the semiconductor ZnAl2O4 were prepared using a microwave-assisted wet chemistry method in the presence of ethylenediamine and calcination at 250 °C. The material’s crystallinity and purity were verified by X-ray diffraction. The pure phase of the ZnAl2O4 presented a cubic crystalline structure with cell parameters a = 8.087 Å and space group Fd-3m (227). Dynamic tests in propane atmospheres were carried out on pellets (~500 µm in diameter) manufactured with ZnAl2O4 powders. In the tests, the oxide showed variations with time in electrical resistance when injecting air-propane at an operating temperature of 250 °C. The pellets showed good stability, high sensitivity, and an optimal dynamic response as a function of time. On the other hand, a mathematical model was proposed to describe the chemical sensor’s dynamic behavior based on the electrical response and linear systems theory. The sensor’s transient response was obtained with the model by exposing the oxide to air and propane gas; its stability was checked, and the stabilization time was calculated. Subsequently, an operating point was selected, and, with it, a propane gas detector was designed. The sensor operated flawlessly at 250 °C at a concentration of 1000 ppm, with a response time of three seconds. The developed device is inexpensive and easy to implement.
Safeguarding the identity of people in photographs or videos published through social networks or television is of great importance to those who do not wish to be recognized. In this paper, a face detecting and coding system is designed with the goal of solving this problem. Mathematical models to generate chaotic orbits are deployed. One of them applies the diffusion technique to scramble the pixels of each face while another implements the confusion technique to alter the relation between plain text and ciphered text. Afterward, another two orbits are utilized for the steganography technique to modify the least significant bit (LSB) to conceal data that would allow authorized users to decipher the faces. To verify the robustness of the proposed encryption algorithm, different tests are performed with the Lena standard image, such as correlation diagrams, histograms, and entropy. In addition, occlusion, noise, and plain image attacks are performed. The results are compared with those of other works, and the proposed system provided high sensitivity at secret key and a large space for the encryption keys, good speed for ciphering, disorder in the cryptogram, security, data integrity, and robustness against different attacks.
Nowadays the interoperability of web applications is carried out by the use of data exchange formats such as XML and JavaScript Object Notation (JSON). Due to its simplicity, JSON objects are the most common way for sending information over the HTTP protocol. With the aim of adding a security mechanism to JSON objects, in this work we propose an encryption approach for cipher JSON objects through the use of chaotic synchronization. Synchronization ability between two chaotic systems offers the possibility of securing information between two points. Our approach includes mechanisms for diffusing and confusing JSON objects (plaintext), which yields a proper ciphertext. Our approach can be applied as an alternative to the existing securing JSON approaches such as JSON Web Encryption (JWE).
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