Bismuth ferrite (BFO) is the drosophila of research in multiferroic materials due to its simultaneous magnetic and electric ordering at room temperature. The unfortunate detail is its antiferromagnetic ordering, which practically cancels magnetization and magnetoelectric coupling of the crystals. To induce finite coupling, dopants have been introduced with a certain success so far. Nanoparticles (NPs) can additionally constrain the formation of the magnetic cycloid in BFO due to size confinement. Doping nanoparticles can thus potentially provide a sizeable magnetization of BFO, making applications in computer memories and hyperthermia cancer treatment feasible. We show that the codoping of BFO NPs by Ba and Mn balances the electrochemical equilibrium, reduces the particle size, and shifts the magnetic phase transition to lower temperatures. The ferroelectric properties are retained and the remanent magnetization is increased by 1 order of magnitude: Bi 0.95 Ba 0.05 Fe 0.95 Mn 0.05 O 3 possesses a remanent magnetization of 0.277 Am 2 /kg. Our Mossbauer studies reveal that two effects drive this increase: partial destruction of the spin cycloid due to Mn and increased spin canting due to Ba doping inducing local stress fields. This dopant combination and particular concentration improve the effective magnetization value exceptionally well.

To study the effects of different temperatures and particle sizes on the anharmonic cycloidal spin structure in BiFeO3 nanoparticles, Mössbauer spectroscopy was applied to three sets of particles with different mean diameters in the range of 54 nm to 1.6 μm at temperatures between 4.2 and 800 K. The paramagnetic transition showed a distinct broadening upon decreasing particle size with Néel temperatures decreasing from 652 to 631 K. The anharmonicity of the long-range cycloidal structure, calculated from experimental Mössbauer spectra, is revealed to decrease upon rising temperature, starting at 150-200 K and reaching the harmonic state at about 400 K.

The ferroelectric and magnetic behaviour of multiferroic BiFeO₃ nanoparticles has been studied using piezoresponse force microscopy (PFM), Mössbauer spectroscopy and SQUID magnetometry. The results of the PFM studies indicate a decay of the spontaneous polarization with decreasing particle size. Nevertheless, particles with diameter ∼50 nm still manifest ferroelectric behaviour. At the same time these particles are weakly ferromagnetic. The Mössbauer spectroscopy studies prove that the weak ferromagnetic state is due to non-compensated surface spins rather than distortions of the cycloidal spin structure characteristic for bulk BiFeO₃.

Structural transformations of CsPbBr₃ were studied by multiple techniques (dielectric, Raman, EPR spectroscopy and XRD) in an extended temperature range.

Laser fragmentation of colloidal submicron-sized bismuth ferrite particles was performed by irradiating a liquid jet to synthesize bismuth ferrite nanoparticles. This treatment achieved a size reduction from 450 nm to below 10 nm. A circular and an elliptical fluid jet were compared to control the energy distribution within the fluid jet and thereby the product size distribution and educt decomposition. The resulting colloids were analysed via UV-VIS, XRD and TEM. All methods were used to gain information on size distribution, material morphology and composition. It was found that using an elliptical liquid jet during the laser fragmentation leads to a slightly smaller and narrower size distribution of the resulting product compared to the circular jet.

The ferroelectricity of multivalent codoped Bismuth ferrite (BiFeO3; BFO) nanoparticles (NPs) is revealed and utilized for photocatalysis, exploiting their narrow electronic bandgap. The photocatalytic activity of ferroelectric photocatalysts BiFe0.95Mn0.05O3 (BFM) NPs and mono‐, di‐, or tri‐valent cations (Ag+, Ca2+, Dy3+; MDT) coincorporated BFM NPs are studied under ultrasonication and in acidic conditions. It is found that such doping enhances the photocatalytic activity of the ferroelectric NPs approximately three times. The correlation of the photocatalytic activity with structural, optical, and electrical properties of the doped NPs is established. The increase of spontaneous polarization by the mono‐ and tri‐valent doping is one of the major factors in enhancing the photocatalytic performance along with other factors such as stronger light absorption in the visible range, low recombination rate of charge carriers, and larger surface area of NPs. A‐site doping of BFO NPs by divalent elements suppresses the polarization, whereas trivalent (Dy3+) and monovalent (Ag+) cations provide an increase of polarization. The depolarization field in these single domain NPs acts as a driving force to mitigate recombination of the photoinduced charge carriers.

The escalated photocatalytic (PC) efficiency of the visible light absorber Ba-doped BiFe0.95Mn0.05O3 (BFM) nanoparticles (NPs) as compared to BiFeO3 (BFO) NPs is reported for the degradation of the organic pollutants rhodamine B and methyl orange.

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