Biological filters are wastewater treatment systems that contain a granular filling material, which form an active biological film that contribute to the biooxidation of impurities from the wastewater. Recent research in the field aimed to improve the classical treatment facilities with aerobic fixed film by using inexpensive and easily accessible materials as filterable loading. Experiments have been carried out on biological filters loaded with volcanic tuff, with a diameter between 20-100 mm, supplied with municipal wastewater from primary settling. The biological filtration efficiency has been etablished throughout the continuous functioning of the experimental installation by physico-chemical water analysis. The analyzed indicators have been the ones stipulated by the legislation in force, namely: pH, chemical oxygen demand (COD), biochemical oxygen demand (BOD5), total suspended matter (TS), total nitrogen (TN), total phosphorus (TP), etc. The analysed wastewater samples have been average samples. The treatment efficiency have been calculated in various hypotheses, depending on the: installation capacity, hydraulic loading, organic loading.
The complex between protoporphyrin IX and zinc was immobilized on nanocarbon paste and on nanodiamond paste to design two stochastic microsensors. The microsensors were used for the recognition and analysis of antibiotics: amoxicillin, ampicillin, and biotin in water samples. Stochastic sensors provided different signatures for the three antibiotics making possible their simultaneous recognition and assay in water samples. Low limits of determination 0.3 pg/mL for amoxicillin and ampicillin, and 0.21 pg/mL for biotin were obtained when nanocarbon paste was used, and 0.03 pg/mL for amoxicillin, 0.30 pg/mL for ampicillin, and 2.14 fg/mL for biotin were obtained when nanodiamond paste was used. Recoveries higher than 99.32 % with RSD lower than 1.00 % were obtained for the assay of the antibiotics in water samples.
The purpose of this paper is the experimental analysis of the thermoelectric power plant Grozavesti impact on Bucharest urban agglomeration for year 2015. Experimental research is done for the NOx and SO2 pollutant for all seasons. The thermoelectric power plant Grozavesti is located near the Botanical Garden. Data provided by the industrial source are processed and constitute the input for the determination of the NOx and SO2 concentrations by using the OML (Operational Local Model) air quality dispersion Gaussian model. The results from modelling shows that the highest NOx and SO2 concentrations occur in the winter and autumn periods, due to unfavorable meteorological dispersion conditions and due to the operation of thermal power plant Grozavesti in the cold seasons. Thermoelectric power plants Grozavesti, operate on natural gas, because power plant have been refurbished. Generally, the results show that the industrial power plant represent the main contributions for pollution when the NOx and SO2 are exceed the limit value, according to Law 104/2011- ambient air quality, and this affect vegetation and human health.
Electroplating sludge resulting from wastewater (washing wastewater and technological solutions) treatment is considered to be a hazardous waste, being a mixture of hydroxides of many heavy metals such us: iron, chromium, copper, nickel, cadmium or zinc. The metal compounds from electroplating sludge have a great economic value, thus, a number of techniques have been investigated in order to recover them. This paper presents the results of the research activity in the laboratory in order to recover Fe (II, III, VI) from two types of electroplating sludge: a fresh sludge from wastewaters treatment and an old sludge, stabilized by disposal for many years. Iron recovery was performed by the solubilization of the sludge in several stages, to yield hydroxides or metal salts of chromium, iron, or zinc. The iron recovery has been performed from the cake obtained after the chromium recovery. In this cake, the iron is present in the form of divalent, trivalent and hexavalent iron. The iron recovery yield was 98.50% from fresh sludge (recovery in one stage) and 96.80% from old sludge (recovery in two stages).
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